Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

被引：204
|
作者：
Zhang, Lei [1 ]
Peng, Dongjie [1 ]
Leng, Xuebing [1 ]
Huang, Zheng [1 ]
机构：
[1] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 13期
关键词：
alkylboronates; homogeneous catalysis; hydroboration; iron; synthetic methods; C-H ACTIVATION; DEHYDROGENATIVE BORYLATION; ORGANIC-SYNTHESIS; CARBON-MONOXIDE; ALKYL-HALIDES; VINYL ARENES; RHODIUM; CATECHOLBORANE; COMPLEXES; HYDROGENATION;
D O I：
10.1002/anie.201210347
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Precious iron: A new PNN iron complex has been developed for use in an iron-catalyzed alkene hydroboration reaction under mild conditions. The environmentally friendly and earth-abundant iron catalyst system is superior to precious-metal systems in terms of efficiency and selectivity for α-olefin hydroborations with pinacolborane. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3676 / 3680
页数：5
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