Vapor-liquid equilibria of binary mixtures containing an alcohol and a branched ether.: Experimental results and modeling

被引：22

作者：

Kammerer, K ^{[1
]}

Schnabel, S ^{[1
]}

Silkenbäumer, D ^{[1
]}

Lichtenthaler, RN ^{[1
]}

机构：

[1] Univ Heidelberg, Inst Phys Chem, D-69120 Heidelberg, Germany

来源：

FLUID PHASE EQUILIBRIA | 1999年 / 162卷 / 1-2期

关键词：

VLE; ether; alcohol; mixtures; thermodynamics; UNIQUAC model; ERAS model;

D O I：

10.1016/S0378-3812(99)00224-1

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Experimental data of vapor-liquid equilibria (VLE) are reported for binary mixtures of ethanol +1,1-dimethylethyl ethyl ether (ETBE) at 313.15, 333.15, 353.15, and 373.15 K. The experimental data as well as data for the systems methanol + 1,1-dimethylethyl methyl ether (MTBE) and methanol + 1,1-dimethylpropyl methyl ether (TAME) taken from literature are used to test the applicability of the UNIQUAC and the ERAS model to describe VLE. The benefits and drawbacks of both models are discussed. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：289 / 301

页数：13

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