Polyhedral Oligomeric Silsesquioxane (POSS)-Containing Polymer Nanocomposites

被引:312
作者
Ayandele, Ebunoluwa [1 ]
Sarkar, Biswajit [1 ]
Alexandridis, Paschalis [1 ]
机构
[1] SUNY Buffalo, Dept Chem & Biol Engn, Buffalo, NY 14260 USA
基金
美国国家科学基金会;
关键词
inorganic-organic nanocomposites; polyhedral oligomeric silsesquioxane (POSS); hybrid polymer; mechanical properties; thermal stability; AMPHIPHILIC BLOCK-COPOLYMER; TRIBLOCK COPOLYMERS; TRANSPORT-PROPERTIES; THERMAL-PROPERTIES; PHASE-BEHAVIOR; T-G; POSS; MORPHOLOGY; OXIDE); NANOSTRUCTURES;
D O I
10.3390/nano2040445
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hybrid materials with superior structural and functional properties can be obtained by incorporating nanofillers into polymer matrices. Polyhedral oligomeric silsesquioxane (POSS) nanoparticles have attracted much attention recently due to their nanometer size, the ease of which these particles can be incorporated into polymeric materials and the unique capability to reinforce polymers. We review here the state of POSS-containing polymer nanocomposites. We discuss the influence of the incorporation of POSS into polymer matrices via chemical cross-linking or physical blending on the structure of nanocomposites, as affected by surface functional groups, and the POSS concentration.
引用
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页码:445 / 475
页数:31
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