Polyhedral Oligomeric Silsesquioxane (POSS)-Containing Polymer Nanocomposites

被引:325
作者
Ayandele, Ebunoluwa [1 ]
Sarkar, Biswajit [1 ]
Alexandridis, Paschalis [1 ]
机构
[1] SUNY Buffalo, Dept Chem & Biol Engn, Buffalo, NY 14260 USA
基金
美国国家科学基金会;
关键词
inorganic-organic nanocomposites; polyhedral oligomeric silsesquioxane (POSS); hybrid polymer; mechanical properties; thermal stability; AMPHIPHILIC BLOCK-COPOLYMER; TRIBLOCK COPOLYMERS; TRANSPORT-PROPERTIES; THERMAL-PROPERTIES; PHASE-BEHAVIOR; T-G; POSS; MORPHOLOGY; OXIDE); NANOSTRUCTURES;
D O I
10.3390/nano2040445
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hybrid materials with superior structural and functional properties can be obtained by incorporating nanofillers into polymer matrices. Polyhedral oligomeric silsesquioxane (POSS) nanoparticles have attracted much attention recently due to their nanometer size, the ease of which these particles can be incorporated into polymeric materials and the unique capability to reinforce polymers. We review here the state of POSS-containing polymer nanocomposites. We discuss the influence of the incorporation of POSS into polymer matrices via chemical cross-linking or physical blending on the structure of nanocomposites, as affected by surface functional groups, and the POSS concentration.
引用
收藏
页码:445 / 475
页数:31
相关论文
共 107 条
[1]   End-Grafted Polymer Chains onto Inorganic Nano-Objects [J].
Achilleos, Demetra S. ;
Vamvakaki, Maria .
MATERIALS, 2010, 3 (03) :1981-2026
[2]   Structural polymorphism of poly(ethylene oxide)-poly(propylene oxide) block copolymers in nonaqueous polar solvents [J].
Alexandridis, P .
MACROMOLECULES, 1998, 31 (20) :6935-6942
[3]   A record nine different phases (four cubic, two hexagonal, and one lamellar lyotropic liquid crystalline and two micellar solutions) in a ternary isothermal system of an amphiphilic block copolymer and selective solvents (water and oil) [J].
Alexandridis, P ;
Olsson, U ;
Lindman, B .
LANGMUIR, 1998, 14 (10) :2627-2638
[4]   MICELLIZATION OF POLY(ETHYLENE OXIDE)-POLY(PROPYLENE OXIDE)-POLY(ETHYLENE OXIDE) TRIBLOCK COPOLYMERS IN AQUEOUS-SOLUTIONS - THERMODYNAMICS OF COPOLYMER ASSOCIATION [J].
ALEXANDRIDIS, P ;
HOLZWARTH, JF ;
HATTON, TA .
MACROMOLECULES, 1994, 27 (09) :2414-2425
[5]   Lyotropic liquid crystallinity in amphiphilic block copolymers: Temperature effects on phase behavior and structure for poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) copolymers of different composition [J].
Alexandridis, P ;
Zhou, DL ;
Khan, A .
LANGMUIR, 1996, 12 (11) :2690-2700
[6]   Design of polymer nanocomposites in solution by polymer functionalization [J].
Anderson, J. A. ;
Sknepnek, R. ;
Travesset, A. .
PHYSICAL REVIEW E, 2010, 82 (02)
[7]   Nanoparticle polymer composites: Where two small worlds meet [J].
Balazs, Anna C. ;
Emrick, Todd ;
Russell, Thomas P. .
SCIENCE, 2006, 314 (5802) :1107-1110
[8]   Block copolymer nanocomposites: Perspectives for tailored functional materials [J].
Bockstaller, MR ;
Mickiewicz, RA ;
Thomas, EL .
ADVANCED MATERIALS, 2005, 17 (11) :1331-1349
[9]   Plug and play polymers. Thermal and X-ray characterizations of noncovalently grafted polyhedral oligomeric silsesquioxane (POSS) - Polystyrene nanocomposites [J].
Carroll, JB ;
Waddon, AJ ;
Nakade, H ;
Rotello, VM .
MACROMOLECULES, 2003, 36 (17) :6289-6291
[10]   Coarse-grained force field for simulating polymer-tethered silsesquioxane self-assembly in solution [J].
Chan, Elaine R. ;
Striolo, Alberto ;
McCabe, Clare ;
Cummings, Peter T. ;
Glotzer, Sharon C. .
JOURNAL OF CHEMICAL PHYSICS, 2007, 127 (11)