Origin and effect of lateral cracks in oxide scales formed on zirconium alloys

被引:65
作者
Tejland, Pia [1 ]
Andren, Flans-Olof [1 ]
机构
[1] Chalmers Univ Technol, Dept Appl Phys, SE-41296 Gothenburg, Sweden
关键词
SYNCHROTRON-RADIATION; OXIDATION; CORROSION; MICROSCOPY; BEHAVIOR; ZIRCALOY; MATRIX; FIB;
D O I
10.1016/j.jnucmat.2012.06.039
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Two varieties of Zircaloy-2, with different second phase particle (SPP) size distributions and different corrosion resistance, were oxidized in a steam autoclave. Transmission electron microscopy was used for investigation of the fine-scale lateral cracks present in the oxide scales. Crack quantification was performed and the number of cracks was correlated with the number of SPPs. A mechanism for crack formation is presented, in which the driving force is the local tensile stresses in the oxide close to the oxide/metal interface, and the initiation sites are un-oxidized SPPs located within this stress field. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:64 / 71
页数:8
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