Mannich Base as Corrosion Inhibitors for N80 Steel in a CO2 Saturated Solution Containing 3 wt % NaCl

被引:28
|
作者
Tang, Mingjin [1 ]
Li, Jianbo [1 ]
Li, Zhida [2 ]
Fu, Luoping [1 ]
Zeng, Bo [1 ]
Lv, Jie [1 ]
机构
[1] Southwest Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Sichuan, Peoples R China
[2] Univ Adelaide, Fac Engn Comp & Math Sci, Adelaide, SA 5005, Australia
关键词
corrosion inhibitor; electrochemical; AFM; CO2; corrosion; MILD-STEEL; CARBON-STEEL; DERIVATIVES; SCALE; OIL;
D O I
10.3390/ma12030449
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, a corrosion inhibitor containing nitrogen atoms and a conjugated bond was synthesised, and its final product synthesised by the optimal conditions of the orthogonal test results is named multi-mannich base (MBT). The corrosion inhibition effect on the N80 steel sheet of the corrosion inhibitor was evaluated in a CO2 saturated solution containing 3 wt % NaCl; the corrosion rate was 0.0446 mm/a and the corrosion inhibition rate was 90.4%. Through electrochemical and adsorption theory study, MBT is a mixed corrosion inhibitor that mainly shows cathode suppression capacity. The adsorption of MBT on the surface of the steel sheet follows the Langmuir adsorption isotherm; it can be spontaneously adsorbed on the surface of the N80 steel sheet, which has a good corrosion inhibition effect. The surface of the N80 steel sheet was microscopically characterised by atomic force microscope (AFM). It can be seen from the results that the N80 steel sheet with MBT added is significantly different from the blank control group; the surface of the steel sheet is relatively smooth, indicating that MBT forms an effective protective film on the surface of N80 steel, which inhibits the steel sheet.
引用
收藏
页数:15
相关论文
共 50 条
  • [1] Interaction of inhibitors with corrosion scale formed on N80 steel in CO2-saturated NaCl solution
    Liu, D.
    Qiu, Y. B.
    Tomoe, Y.
    Bando, K.
    Guo, X. P.
    MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2011, 62 (12): : 1153 - 1158
  • [2] Macrocyclic inhibitor for corrosion of N80 steel in 3.5% NaCl solution saturated with CO2
    Singh, Ambrish
    Lin, Yuanhua
    Obot, I. B.
    Ebenso, Eno E.
    JOURNAL OF MOLECULAR LIQUIDS, 2016, 219 : 865 - 874
  • [3] Inhibition effect of pomelo peel extract for N80 steel in 3.5% NaCl saturated with CO2 solution
    Sun, Zhipeng
    Singh, Ambrish
    Xu, Xihua
    Chen, Songsong
    Liu, Wanying
    Lin, Yuanhua
    RESEARCH ON CHEMICAL INTERMEDIATES, 2017, 43 (11) : 6719 - 6736
  • [4] Synergistic effect of Mannich base and sodium tungstate as corrosion inhibition for N80 steel
    Wang Yun
    Hu Jun
    Wang Tian-tian
    Zheng Mao-sheng
    CAILIAO GONGCHENG-JOURNAL OF MATERIALS ENGINEERING, 2019, 47 (02): : 122 - 128
  • [5] Crevice corrosion of N80 carbon steel in CO2-saturated environment containing acetic acid
    Li, Y. Z.
    Xu, N.
    Liu, G. R.
    Guo, X. P.
    Zhang, G. A.
    CORROSION SCIENCE, 2016, 112 : 426 - 437
  • [6] Synergistic effect of stress and crevice on the corrosion of N80 carbon steel in the CO2-saturated NaCl solution containing acetic acid
    Li, Y. Z.
    Guo, X. P.
    Zhang, G. A.
    CORROSION SCIENCE, 2017, 123 : 228 - 242
  • [7] Influence of CO2 partial pressure and flow rate on the corrosion behavior of N80 steel in 3.5% NaCl
    Chen, Xuezhong
    Yang, Xiaomin
    Zeng, Mingyou
    Wang, Hu
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2023, 18 (08):
  • [8] Inhibition effect of imidazoline inhibitor on the crevice corrosion of N80 carbon steel in the CO2-saturated NaCl solution containing acetic acid
    Li, Y. Z.
    Xu, N.
    Guo, X. P.
    Zhang, G. A.
    CORROSION SCIENCE, 2017, 126 : 127 - 141
  • [9] The behavior of pre-corrosion effect on the performance of imidazoline-based inhibitor in 3 wt.% NaCl solution saturated with CO2
    Zhang, Huan-huan
    Pang, Xiaolu
    Zhou, Meng
    Liu, Chao
    Wei, Liang
    Gao, Kewei
    APPLIED SURFACE SCIENCE, 2015, 356 : 63 - 72
  • [10] Pectin-amino acid derivatives as highly efficient inhibitors for the corrosion of N80 steel in CO2-saturated formation water
    Wang, Dan-Yang
    Wang, Jun-Hu
    Li, Hui-Jing
    Wu, Yan-Chao
    INDUSTRIAL CROPS AND PRODUCTS, 2022, 189