Mannich Base as Corrosion Inhibitors for N80 Steel in a CO2 Saturated Solution Containing 3 wt % NaCl

被引:30
作者
Tang, Mingjin [1 ]
Li, Jianbo [1 ]
Li, Zhida [2 ]
Fu, Luoping [1 ]
Zeng, Bo [1 ]
Lv, Jie [1 ]
机构
[1] Southwest Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Sichuan, Peoples R China
[2] Univ Adelaide, Fac Engn Comp & Math Sci, Adelaide, SA 5005, Australia
关键词
corrosion inhibitor; electrochemical; AFM; CO2; corrosion; MILD-STEEL; CARBON-STEEL; DERIVATIVES; SCALE; OIL;
D O I
10.3390/ma12030449
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, a corrosion inhibitor containing nitrogen atoms and a conjugated bond was synthesised, and its final product synthesised by the optimal conditions of the orthogonal test results is named multi-mannich base (MBT). The corrosion inhibition effect on the N80 steel sheet of the corrosion inhibitor was evaluated in a CO2 saturated solution containing 3 wt % NaCl; the corrosion rate was 0.0446 mm/a and the corrosion inhibition rate was 90.4%. Through electrochemical and adsorption theory study, MBT is a mixed corrosion inhibitor that mainly shows cathode suppression capacity. The adsorption of MBT on the surface of the steel sheet follows the Langmuir adsorption isotherm; it can be spontaneously adsorbed on the surface of the N80 steel sheet, which has a good corrosion inhibition effect. The surface of the N80 steel sheet was microscopically characterised by atomic force microscope (AFM). It can be seen from the results that the N80 steel sheet with MBT added is significantly different from the blank control group; the surface of the steel sheet is relatively smooth, indicating that MBT forms an effective protective film on the surface of N80 steel, which inhibits the steel sheet.
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页数:15
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