On Demand: The Singular rht Net, an Ideal Blueprint for the Construction of a Metal-Organic Framework (MOF) Platform

被引：117
作者：
Eubank, Jarrod F. [2 ]
Nouar, Farid [2 ]
Luebke, Ryan [1 ]
Cairns, Amy J. [1 ]
Wojtas, Lukasz [2 ]
Alkordi, Mohamed [1 ]
Bousquet, Till [2 ]
Hight, Matthew R. [2 ]
Eckert, Juergen [2 ]
Embs, Jan P. [3 ]
Georgiev, Peter A. [4 ]
Eddaoudi, Mohamed [1 ,2 ]
机构：
[1] King Abdullah Univ Sci & Technol, KAUST Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia
[2] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
[3] Paul Scherrer Inst, Neutron Scattering Lab, Villigen, Switzerland
[4] Univ Milan, Dept Struct Chem, I-20122 Milan, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 40期
关键词：
controlled porosity; hybrid materials; metal-organic frameworks; reticular chemistry; supermolecular building blocks; CARBON-DIOXIDE CAPTURE; POSTSYNTHETIC MODIFICATION; RETICULAR CHEMISTRY; BUILDING-BLOCKS; DESIGN; POLYHEDRA; DATABASE; UNITS; CO2;
D O I：
10.1002/anie.201201202
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The exceptional nature of the rht-MOF platform, based on a singular edge-transitive net (the only net for the combination of 3- and 24-connected nodes), makes it an ideal target in crystal chemistry. The high level of control indicates an unparalleled blueprint for isoreticular functional materials (without concern for interpenetration) for targeted applications. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：10099 / 10103
页数：5
相关论文
共 35 条
  • [1] The Cambridge Structural Database: a quarter of a million crystal structures and rising
    Allen, FH
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1): : 380 - 388
  • [2] [Anonymous], 2010, Metal-Organic Frameworks: Design and Application
  • [3] Caskey S. R., 2009, MAT MATTERS, V4.4, P111
  • [4] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage
    Eddaoudi, M
    Kim, J
    Rosi, N
    Vodak, D
    Wachter, J
    O'Keeffe, M
    Yaghi, OM
    [J]. SCIENCE, 2002, 295 (5554) : 469 - 472
  • [5] Porous metal-organic polyhedra:: 25 Å cuboctahedron constructed from 12 Cu2(CO2)4 paddle-wheel building blocks
    Eddaoudi, M
    Kim, J
    Wachter, JB
    Chae, HK
    O'Keeffe, M
    Yaghi, OM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (18) : 4368 - 4369
  • [6] Eddaoudi M., 2009, U. S. Pat. Appl. Publ., Patent No. [US 20090143596A1, 20090143596]
  • [7] Building units design and scale chemistry
    Férey, G
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2000, 152 (01) : 37 - 48
  • [8] Isoreticular Expansion of Metal-Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals
    Furukawa, Hiroyasu
    Go, Yong Bok
    Ko, Nakeun
    Park, Young Kwan
    Uribe-Romo, Fernando J.
    Kim, Jaheon
    O'Keeffe, Michael
    Yaghi, Omar M.
    [J]. INORGANIC CHEMISTRY, 2011, 50 (18) : 9147 - 9152
  • [9] Metal-Organic Frameworks as Adsorbents for Hydrogen Purification and Precombustion Carbon Dioxide Capture
    Herm, Zoey R.
    Swisher, Joseph A.
    Smit, Berend
    Krishna, Rajamani
    Long, Jeffrey R.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (15) : 5664 - 5667
  • [10] Large H2 storage capacity of a new polyhedron-based metal-organic framework with high thermal and hygroscopic stability
    Hong, Seunghee
    Oh, Minhak
    Park, Mira
    Yoon, Ji Woong
    Chang, Jong-San
    Lah, Myoung Soo
    [J]. CHEMICAL COMMUNICATIONS, 2009, (36) : 5397 - 5399
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