Comparison of the benzene sorption properties of metal organic frameworks: influence of the textural properties

被引:9
作者
Belarbi, Hichem [1 ,2 ]
Gonzales, Philippe [1 ]
Basta, Altaf [3 ]
Trens, Philippe [1 ]
机构
[1] Ecole Natl Super Chim Montpellier, UMR CNRS 5253, Inst Charles Gerhardt, 204 Ave E Jeanbrau, F-34296 Montpellier 5, France
[2] Univ Oran, Oran, Algeria
[3] Natl Res Ctr, El Bohous St, Cairo, Egypt
关键词
POROUS MATERIAL MIL-101(CR); N-HEXANE; CU-BTC; ADSORPTION; SEPARATION; ISOMERS; VAPORS;
D O I
10.1039/c8em00481a
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The adsorption of benzene by CuBTC and MIL101(Cr) is investigated. The differences between both materials are discussed in terms of porous volume and affinities, determined by calculating Henry's constants and by measuring the adsorption enthalpies. If MIL101(Cr) adsorbs higher quantities of benzene, CuBTC develops stronger interaction, interesting for VOC remediation.
引用
收藏
页码:407 / 412
页数:6
相关论文
共 31 条
  • [1] [Anonymous], 2000, IARC MONOGRAPH S, P120
  • [2] Atmospheric chemistry of VOCs and NOx
    Atkinson, R
    [J]. ATMOSPHERIC ENVIRONMENT, 2000, 34 (12-14) : 2063 - 2101
  • [3] Toxic gas removal - metal-organic frameworks for the capture and degradation of toxic gases and vapours
    Barea, Elisa
    Montoro, Carmen
    Navarro, Jorge A. R.
    [J]. CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) : 5419 - 5430
  • [4] Prussian Blue Analogues for the Separation of Hydrocarbons in Humid Conditions
    Boudjema, Lotfi
    Mamontova, Ekaterina
    Long, Jerome
    Larionova, Joulia
    Guari, Yannick
    Trens, Philippe
    [J]. INORGANIC CHEMISTRY, 2017, 56 (14) : 7598 - 7601
  • [5] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n
    Chui, SSY
    Lo, SMF
    Charmant, JPH
    Orpen, AG
    Williams, ID
    [J]. SCIENCE, 1999, 283 (5405) : 1148 - 1150
  • [6] A chromium terephthalate-based solid with unusually large pore volumes and surface area
    Férey, G
    Mellot-Draznieks, C
    Serre, C
    Millange, F
    Dutour, J
    Surblé, S
    Margiolaki, I
    [J]. SCIENCE, 2005, 309 (5743) : 2040 - 2042
  • [7] Amine grafting on coordinatively unsaturated metal centers of MOFs:: Consequences for catalysis and metal encapsulation
    Hwang, Young Kyu
    Hong, Do-Young
    Chang, Jong-San
    Jhung, Sung Hwa
    Seo, You-Kyong
    Kim, Jinheung
    Vimont, Alexandre
    Daturi, Marco
    Serre, Christian
    Ferey, Gerard
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (22) : 4144 - 4148
  • [8] A review on nanomaterials for environmental remediation
    Khin, Mya Mya
    Nair, A. Sreekumaran
    Babu, V. Jagadeesh
    Murugan, Rajendiran
    Ramakrishna, Seeram
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (08) : 8075 - 8109
  • [9] Selective gas adsorption and separation in metal-organic frameworks
    Li, Jian-Rong
    Kuppler, Ryan J.
    Zhou, Hong-Cai
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) : 1477 - 1504
  • [10] Effect of Oxyfluorination of Activated Carbon Fibers on Adsorption of Benzene Gas Causing Sick House Syndrome
    Lim, Hyung Soon
    Kim, Min-Ji
    Kong, Eun Young
    Jeong, Jin-do
    Lee, Young-Seak
    [J]. APPLIED CHEMISTRY FOR ENGINEERING, 2018, 29 (03): : 312 - 317