Controlling molecular assembly in two dimensions:: The concentration dependence of thermally induced 2D aggregation of molecules on a metal surface

被引：132
作者：
Stöhr, M
Wahl, M
Galka, CH
Riehm, T
Jung, TA
Gade, LH
机构：
[1] Univ Basel, NCCR Nanoscale Sci & Inst Phys, CH-4056 Basel, Switzerland
[2] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany
[3] Paul Scherrer Inst, Lab Micro & Nanostruct, CH-5232 Villigen, Switzerland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 45期
关键词：
dilution principle; hydrogen bonds; molecular aggregation; scanning probe microscopy; surface chemistry;
D O I：
10.1002/anie.200502316
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Dilution principle in two dimensions: One building block yields three forms of aggregation on variation of the surface concentration of the molecular precursor (see picture; ML = monolayer coverage). Upon annealing at 300°C, highly robust 2D aggregates are obtained on metal surfaces which lend themselves to the construction of hierarchic systems of higher complexity. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：7394 / 7398
页数：5
相关论文
共 38 条
[1]  
[Anonymous], SCIENCE
[2]   Time evolution analysis of a 2D solid-gas equilibrium:: a model system for molecular adsorption and diffusion [J].
Berner, S ;
Brunner, M ;
Ramoino, L ;
Suzuki, H ;
Güntherodt, HJ ;
Jung, TA .
CHEMICAL PHYSICS LETTERS, 2001, 348 (3-4) :175-181
[3]   Supramolecular patterned surfaces driven by cooperative assembly of C60 and porphyrins on metal substrates [J].
Bonifazi, D ;
Spillmann, H ;
Kiebele, A ;
de Wild, M ;
Seiler, P ;
Cheng, FY ;
Güntherodt, HJ ;
Jung, T ;
Diederich, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (36) :4759-4763
[4]  
BONIFAZI D, 2004, ANGEW CHEM, V116, P4863
[5]   Supramolecular polymers [J].
Brunsveld, L ;
Folmer, BJB ;
Meijer, EW ;
Sijbesma, RP .
CHEMICAL REVIEWS, 2001, 101 (12) :4071-4097
[6]   Two-dimensional supramolecular self-assembly probed by scanning tunneling microscopy [J].
De Feyter, S ;
De Schryver, FC .
CHEMICAL SOCIETY REVIEWS, 2003, 32 (03) :139-150
[7]   Supramolecular control of two-dimensional phase behavior [J].
De Feyter, S ;
Larsson, M ;
Schuurmans, N ;
Verkuijl, B ;
Zoriniants, G ;
Gesquière, A ;
Abdel-Mottaleb, MM ;
van Esch, J ;
Feringa, BL ;
van Stam, J ;
De Schryver, F .
CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (05) :1198-1206
[8]  
de Wild M, 2002, CHEMPHYSCHEM, V3, P881, DOI 10.1002/1439-7641(20021018)3:10<881::AID-CPHC881>3.0.CO
[9]  
2-P
[10]   Supramolecular assemblies of trimesic acid on a Cu(100) surface [J].
Dmitriev, A ;
Lin, N ;
Weckesser, J ;
Barth, JV ;
Kern, K .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (27) :6907-6912
1234