Ferrocenyl derivatives with Mo(TpAn) units for second- and third-order nonlinear optical applications

被引：11
|
作者：
Rojo, G
Agulló-López, F
Campo, JA
Cano, M [1 ]
Lagunas, MC
Heras, JV
机构：
[1] Univ Complutense, Fac Ciencias Quim, Dept Quim Inorgan 1, E-28040 Madrid, Spain
[2] Univ Complutense, Dept Fis Mat C4, E-28040 Madrid, Spain
来源：
SYNTHETIC METALS | 2001年 / 124卷 / 01期
关键词：
organometallics for NLO; second- and third-harmonic generation; guest-host films;
D O I：
10.1016/S0379-6779(01)00446-5
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
New molecular systems based on donor/acceptor organometallic groups connected by pi -conjugated bridges have been designed and their nonlinear optical (NLO) properties investigated. At macroscopic level SHG and THG responses were measured on corona-poled spin-coated films and at molecular level cubic hyperpolarizability data were obtained from solution. For comparison related compounds having NO, as acceptor group were also analyzed. New trends have been derived from the analysis of the molecular characteristics: nature of the acceptor and structural variations on the bridge. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：201 / 203
页数：3
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