Dye-sensitized solar cells composed of Ti1-xSnxO2 nanocrystals

被引:5
作者
Pang, Aiying [1 ]
Li, Yafeng [1 ]
Zhang, Huixing [1 ]
Wang, Yangzhong [1 ]
Wei, Mingdeng [1 ]
机构
[1] Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China
关键词
Ti1-xSnxO2; Nanocrystal; Dye-sensitized solar cells; Photovoltaic property; EFFICIENCY; CONVERSION; FILMS;
D O I
10.1016/j.matchemphys.2012.03.109
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ti1-xSnxO2 nanocrystals were successfully synthesized by using a simple solvothermal route, and its band energy gap broaden and flat band potential can be rationally regulated with increasing x value. Furthermore, Ti1-xSnxO2 nanocrystals were first used as the photoelectrode material for dye-sensitized solar cells. A cell made of Ti1-xSnxO2 (x = 0.3) exhibited the best photovoltaic performance. This is due to its most narrow band gap energies, most negative flat band potential and lowest dark current densities. After the surface of Ti1-xSnxO2 (x = 0.3) electrode was treated with TiCl4 solution, the cell sensitized by a mixed solution of N719 and D131 dye exhibited the best efficiency of 4.64% under the illumination of 1 sun (AM1.5, 100 mW cm(-2)). (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:46 / 50
页数:5
相关论文
共 34 条
[1]   Photoelectrochemical Study of the Band Structure of Zn2SnO4 Prepared by the Hydrothermal Method [J].
Alpuche-Aviles, Mario A. ;
Wu, Yiying .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (09) :3216-3224
[2]   PREPARATION AND PHOTOELECTROCHEMICAL CHARACTERIZATION OF THIN SNO(2) NANOCRYSTALLINE SEMICONDUCTOR-FILMS AND THEIR SENSITIZATION WITH BIS(2,2'-BIPYRIDINE)(2,2'-BIPYRIDINE-4,4'-DICARBOXYLIC ACID)RUTHENIUM(II) COMPLEX [J].
BEDJA, I ;
HOTCHANDANI, S ;
KAMAT, PV .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (15) :4133-4140
[3]   Nanocrystalline mesoporous strontium titanate as photoelectrode material for photosensitized solar devices:: Increasing photovoltage through flatband potential engineering [J].
Burnside, S ;
Moser, JE ;
Brooks, K ;
Grätzel, M ;
Cahen, D .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (43) :9328-9332
[4]   Nature of photovoltaic action in dye-sensitized solar cells [J].
Cahen, D ;
Hodes, G ;
Grätzel, M ;
Guillemoles, JF ;
Riess, I .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (09) :2053-2059
[5]   Novel thiophene-conjugated indoline dyes for zinc oxide solar cells [J].
Dentani, Takuya ;
Kubota, Yasuhiro ;
Funabiki, Kazumasa ;
Jin, Jiye ;
Yoshida, Tsukasa ;
Minoura, Hideki ;
Miura, Hidetoshi ;
Matsui, Masaki .
NEW JOURNAL OF CHEMISTRY, 2009, 33 (01) :93-101
[6]  
Finklea H.O., 1988, SEMICONDUCTOR ELECTR, V5, P43
[7]   Synthesis of Ti1-xSnxO2 nanosized photocatalysts in reverse microemulsions [J].
Fresno, Fernando ;
Tudela, David ;
Coronado, Juan M. ;
Soria, Javier .
CATALYSIS TODAY, 2009, 143 (3-4) :230-236
[8]   Solar energy conversion by dye-sensitized photovoltaic cells [J].
Grätzel, M .
INORGANIC CHEMISTRY, 2005, 44 (20) :6841-6851
[9]   Photoelectrochemical cells [J].
Grätzel, M .
NATURE, 2001, 414 (6861) :338-344
[10]   Molecular photovoltaics [J].
Hagfeldt, A ;
Grätzel, M .
ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) :269-277