Fabrication of hollow-sphere films of wurtzite CuInS2 on copper substrate

被引：10

作者：

Lei, Shuijin ^{[1
]}

Wang, Chunying ^{[1
]}

Huang, Qiang ^{[2
]}

Liu, Lei ^{[1
]}

Ge, Yang ^{[1
]}

Tang, Qingliu ^{[1
]}

Cheng, Baochang ^{[1
]}

Xiao, Yanhe ^{[1
]}

Zhou, Lang ^{[1
]}

机构：

[1] Nanchang Univ, Sch Mat Sci & Engn, Nanchang 330031, Jiangxi, Peoples R China

[2] Nanchang Univ, Sch Electromech Engn, Nanchang 330031, Jiangxi, Peoples R China

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2013年 / 143卷 / 01期

基金：

中国国家自然科学基金; 高等学校博士学科点专项科研基金;

关键词：

Chalcogenides; Nanostructures; Chemical synthesis; Electron microscopy; CU-IN-S; SOLAR-CELLS; NANOCRYSTALS; NANOPARTICLES; PRECURSORS; SYSTEM; SHAPE;

D O I：

10.1016/j.matchemphys.2013.08.051

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

As important semiconductors, I-III-VI2 compounds have attracted wide attention, among which the wurtzite structured CuInS2 has been the research focus due to its metastable phase. In this paper, the wurtzite CuInS2 hollow-sphere films have been successfully prepared on copper substrate in a self-designed solvothermal detached system. The films of Cu(OH)(2) one-dimensional nanostructure arrays and thioacetamide were used as the precursors and triethylene glycol was used as the solvent. Experiments showed that the amount of indium trichloride played a determinative role in the final morphology of the products. Meanwhile, the one-dimensional nanostructure arrays and the detached solvothermal system have great influences on the crystal shape as well. Based on the experimental results, a possible formation mechanism for the CuInS2 hollow spheres was also proposed. The UV-Vis absorption spectrum showed a broad absorption over the entire visible light and extending into the near-infrared region and presented the band gap of 1.53 eV for the as-prepared wurtzite CuInS2, which indicates the potential applications in solar cells. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：195 / 202

页数：8

共 31 条

[31] Low-Temperature Synthesis of CuInSe2 Nanotube Array on Conducting Glass Substrates for Solar Cell Application [J].

Xu, Jun ;

Luan, Chun-Yan ;

Tang, Yong-Bing ;

Chen, Xue ;

Zapien, Juan Antnio ;

Zhang, Wen-Jun ;

Kwong, Hoi-Lun ;

Meng, Xiang-Min ;

Lee, Shuit-Tong ;

Lee, Chun-Sing .

ACS NANO, 2010, 4 (10) :6064-6070

← 1 2 3 4 →