Absolut "copper catalyzation perfected"; robust living polymerization of NIPAM: Guinness is good for SET-LRP

被引：79

作者：

Waldron, Christopher ^{[1
]}

Zhang, Qiang ^{[1
]}

Li, Zaidong ^{[1
]}

Nikolaou, Vasiliki ^{[1
]}

Nurumbetov, Gabit ^{[1
]}

Godfrey, Jamie ^{[1
]}

McHale, Ronan ^{[1
]}

Yilmaz, Gokhan ^{[1
]}

Randev, Rajan K. ^{[1
]}

Girault, Mony ^{[1
]}

McEwan, Kayleigh ^{[1
]}

Haddleton, David M. ^{[1
]}

Droesbeke, Martijn ^{[1
]}

Haddleton, Alice J. ^{[1
]}

Wilson, Paul ^{[1
]}

Simula, Alexandre ^{[1
]}

Collins, Jennifer ^{[1
]}

Lloyd, Danielle J. ^{[1
]}

Burns, James A. ^{[1
]}

Summers, Christopher ^{[1
]}

Houben, Claudia ^{[1
]}

Anastasaki, Athina ^{[1
]}

Li, Muxiu ^{[1
]}

Becer, C. Remzi ^{[1
]}

Kiviaho, Jenny K. ^{[1
]}

Risangud, Nuttapol ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

POLYMER CHEMISTRY | 2014年 / 5卷 / 01期

关键词：

TRANSFER RADICAL POLYMERIZATION; CLICK CHEMISTRY; POLY(N-ISOPROPYLACRYLAMIDE); POLYMERS; ACRYLATES; WELL;

D O I：

10.1039/c3py01075a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The controlled polymerization of N-isopropyl acrylamide (NIPAM) is reported in a range of international beers, wine, ciders and spirits utilizing Cu(0)-mediated living radical polymerization (SET-LRP). Highly active Cu(0) is first formed in situ by the rapid disproportionation of [Cu(I)(Me-6-Tren)Br] in the commercial water-alcohol mixtures. Rapid, yet highly controlled, radical polymerization follows (D values as low as 1.05) despite the numerous chemicals of diverse functionality present in these solvents e.g. alpha acids, sugars, phenols, terpenoids, flavonoids, tannins, metallo-complexes, anethole etc. The results herein demonstrate the robust nature of the aqueous SET-LRP protocol, underlining its ability to operate efficiently in a wide range of complex chemical environments.

引用

页码：57 / 61

页数：5

共 22 条

[1] Polymerization of long chain [meth]acrylates by Cu(0)-mediated and catalytic chain transfer polymerisation (CCTP): high fidelity end group incorporation and modification [J].

Anastasaki, Athina ;

Waldron, Christopher ;

Nikolaou, Vasiliki ;

Wilson, Paul ;

McHale, Ronan ;

Smith, Timothy ;

Haddleton, David M. .

POLYMER CHEMISTRY, 2013, 4 (15) :4113-4119

[2] The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates [J].

Anastasaki, Athina ;

Waldron, Christopher ;

Wilson, Paul ;

McHale, Ronan ;

Haddleton, David M. .

POLYMER CHEMISTRY, 2013, 4 (09) :2672-2675

[3] Copper(0)- mediated radical polymerisation in a self-generating biphasic system [J].

Boyer, Cyrille ;

Atme, Amir ;

Waldron, Christopher ;

Anastasaki, Athina ;

Wilson, Paul ;

Zetterlund, Per B. ;

Haddleton, David ;

Whittaker, Michael R. .

POLYMER CHEMISTRY, 2013, 4 (01) :106-112

[4] WHAT MAKES CHEMISTRY DIFFICULT - ALTERNATE PERCEPTIONS [J].

CARTER, CS ;

BRICKHOUSE, NW .

JOURNAL OF CHEMICAL EDUCATION, 1989, 66 (03) :223-225

[5] Phase behavior of poly(N-isopropylacrylamide) in binary aqueous solutions [J].

Costa, ROR ;

Freitas, RFS .

POLYMER, 2002, 43 (22) :5879-5885

[6] Determination of total polyphenolic content in red wines by means of the combined He-Ne laser optothermal window and Folin-Ciocalteu colorimetry assay [J].

Dóka, O ;

Bicanic, D .

ANALYTICAL CHEMISTRY, 2002, 74 (09) :2157-2161

[7] Stimuli-reponsive polymers and their bioconjugates [J].

Gil, ES ;

Hudson, SM .

PROGRESS IN POLYMER SCIENCE, 2004, 29 (12) :1173-1222

[8]

Kolb HC, 2001, ANGEW CHEM INT EDIT, V40, P2004, DOI 10.1002/1521-3773(20010601)40:11<2004::AID-ANIE2004>3.3.CO

[9]

2-X

[10] Does Guinness Travel Well? [J].

Kotz, Daniel ;

Glynn, Liam G. ;

Mallen, Christian D. ;

Cals, Jochen W. L. .

JOURNAL OF FOOD SCIENCE, 2011, 76 (02) :S121-S125

← 1 2 3 →