Hydroformylation in Petroleum Chemistry and Organic Synthesis: Implementation of the Process and Solving the Problem of Recycling Homogeneous Catalysts (Review)

被引：34

作者：

Gorbunov, D. N. ^{[1
]}

Volkov, A. V. ^{[2
]}

Kardasheva, Yu. S. ^{[1
]}

Maksimov, A. L. ^{[1
]}

Karakhanov, E. A. ^{[2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow, Russia

[2] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow, Russia

来源：

PETROLEUM CHEMISTRY | 2015年 / 55卷 / 08期

关键词：

hydroformylation; homogeneous catalysis; catalyst recycling; membrane nanofiltration; FLUOROUS BIPHASE HYDROFORMYLATION; SUPERCRITICAL CARBON-DIOXIDE; TEMPERATURE IONIC LIQUIDS; SOLUBLE METAL-COMPLEXES; 2-PHASE HYDROFORMYLATION; SOLVENT NANOFILTRATION; RHODIUM COMPLEXES; 1-BUTYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE; PROPYLENE HYDROFORMYLATION; ACTIVITY-COEFFICIENTS;

D O I：

10.1134/S0965544115080046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methods for isolating and recycling homogeneous hydroformylation catalysts used in the industry and promising research works on the development of novel ligands and selection of solvent systems are surveyed. The role of membrane nanofiltration as one of the possible means of separating a homogeneous catalyst from the reaction mixture is specified.

引用

页码：587 / 603

页数：17

共 179 条

[81]

Herwig J, 2000, CATAL MET C, V22, P189

[82]

Holbrey J. D., 1999, CLEAN PRODUCTS PROCE, V1, P223, DOI DOI 10.1007/S100980050036

[83] FACILE CATALYST SEPARATION WITHOUT WATER - FLUOROUS BIPHASE HYDROFORMYLATION OF OLEFINS [J].

HORVATH, IT ;

RABAI, J .

SCIENCE, 1994, 266 (5182) :72-75

[84] Molecular engineering in homogeneous catalysis:: One-phase catalysis coupled with biphase catalyst separation.: The fluorous-soluble HRh(CO){P[CH2CH2(CF2)5CF3]3}3 hydroformylation system [J].

Horváth, IT ;

Kiss, G ;

Cook, RA ;

Bond, JE ;

Stevens, PA ;

Rábai, J ;

Mozeleski, EJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (13) :3133-3143

[85] HIGH-PRESSURE NMR-STUDIES OF THE WATER-SOLUBLE RHODIUM HYDROFORMYLATION SYSTEM [J].

HORVATH, IT ;

KASTRUP, RV ;

OSWALD, AA ;

MOZELESKI, EJ .

CATALYSIS LETTERS, 1989, 2 (02) :85-90

[86] Performance of octene in fluorous biphasic hydroformylation: octene distribution and reversible transfer between perfluoromethylcyclohexane and nonanal [J].

Huang, YL ;

Perperi, E ;

Manos, G ;

Cole-Hamilton, DJ .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 210 (1-2) :17-21

[87] PROCESS FOR MANUFACTURING 1,4-BUTANEDIOL FROM ACROLEIN [J].

ICHIKAWA, S ;

OHGOMORI, Y ;

SUMITANI, N ;

HAYASHI, H ;

IMANARI, M .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (03) :971-973

[88] Solubility of carbon dioxide, ethane, methane, oxygen, nitrogen, hydrogen, argon, and carbon monoxide in 1-butyl-3-methylimidazolium tetrafluoroborate between temperatures 283 K and 343 K and at pressures close to atmospheric [J].

Jacquemin, J ;

Gomes, MFC ;

Husson, P ;

Majer, V .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2006, 38 (04) :490-502

[89]

James B. R., 2001, AQUEOUS ORGANOMETALL, P152

[90] A novel thermoregulated phosphine ligand used for the Rh-catalyzed hydroformylation of mixed C11-12 olefins in aqueous/organic biphasic system [J].

Ji, Zhi Jiang ;

Jiang, Jing Yang ;

Wang, Yan Hua .

CHINESE CHEMICAL LETTERS, 2010, 21 (05) :515-518

← 4 5 6 7 8 9 10 11 12 13 →