Hydroformylation in Petroleum Chemistry and Organic Synthesis: Implementation of the Process and Solving the Problem of Recycling Homogeneous Catalysts (Review)

被引：34
作者：
Gorbunov, D. N. [1 ]
Volkov, A. V. [2 ]
Kardasheva, Yu. S. [1 ]
Maksimov, A. L. [1 ]
Karakhanov, E. A. [2 ]
机构：
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow, Russia
[2] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow, Russia
来源：
PETROLEUM CHEMISTRY | 2015年 / 55卷 / 08期
关键词：
hydroformylation; homogeneous catalysis; catalyst recycling; membrane nanofiltration; FLUOROUS BIPHASE HYDROFORMYLATION; SUPERCRITICAL CARBON-DIOXIDE; TEMPERATURE IONIC LIQUIDS; SOLUBLE METAL-COMPLEXES; 2-PHASE HYDROFORMYLATION; SOLVENT NANOFILTRATION; RHODIUM COMPLEXES; 1-BUTYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE; PROPYLENE HYDROFORMYLATION; ACTIVITY-COEFFICIENTS;
D O I：
10.1134/S0965544115080046
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Methods for isolating and recycling homogeneous hydroformylation catalysts used in the industry and promising research works on the development of novel ligands and selection of solvent systems are surveyed. The role of membrane nanofiltration as one of the possible means of separating a homogeneous catalyst from the reaction mixture is specified.
引用
收藏
页码：587 / 603
页数：17
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