Zeolite catalyzed ring opening of styrene oxide

被引：20

作者：

Dimitrova, R

Minkov, V

Micheva, N

机构：

[1] Institute of Organic Chemistry, BAS

来源：

APPLIED CATALYSIS A-GENERAL | 1996年 / 145卷 / 1-2期

关键词：

styrene oxide conversion; ZSM-5; ZSM-35; zeolite; Beta; silver exchanged;

D O I：

10.1016/0926-860X(96)00155-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Activation of styrene oxide for ring opening reactions has been achieved over acidic forms of zeolites possessing two dimensional intersecting channels of different sizes (HZSM-5 and HZSM-35), as well as over two silver modifications of the latter. Zeolite type Beta has been tested for determining the influence of the channel structure to the reactions' selectivity. Selective formation of 2-phenylethanol on HZSM-35 has been observed. On the silver modifications of zeolite ZSM-35 significant quantities of phenylacetic acid have been determined together with the expected product 2-phenylethanol.

引用

页码：49 / 55

页数：7

共 10 条

[1]

BEYER H, 1976, J CHEM SOC FARADAY T, V3, P674

[2]

HOLDERICH W, 1985, Patent No. 546372

[3] INVESTIGATION OF THE DISTRIBUTION OF ACIDITY IN ZEOLITES BY TEMPERATURE-PROGRAMMED DESORPTION OF PROBE MOLECULES .1. DEALUMINATED MORDENITES [J].

KARGE, HG ;

DONDUR, V .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (02) :765-772

[4]

MOLNAR A, 1991, J CATAL, V129, P303

[5]

Neri C., 1984, Eur. Pat, Patent No. 0100117

[6]

ORISAKU M, Patent No. 61112040

[7]

PLANK CJ, 1977, Patent No. 4016245

[8] EPOXIDE REARRANGEMENTS ON MINERAL AND SILICA-ALUMINA SURFACES [J].

RUIZHITZKY, E ;

CASAL, B .

JOURNAL OF CATALYSIS, 1985, 92 (02) :291-295

[9] FORMATION OF THE AG-6(X+) CLUSTER IN ZEOLITE-A [J].

SCHOONHEYDT, RA ;

LEEMAN, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (05) :2048-2053

[10]

WADLINGER RL, 1966, Patent No. 3308069

← 1 →