Synthesis and Characterization of N-[1,10-Phenanthroline]-N′-[(Benzo-15-Crown-5)yl] Thiourea and Its Complex with Copper(I)

被引：1
|
作者：
Elmali, Fikriye Tuncel [1 ]
Avciata, Ulvi [1 ]
Demirhan, Nebahat [1 ]
Gul, Ahmet [2 ]
机构：
[1] Yildiz Tech Univ, Fac Arts & Sci, Dept Chem, TR-34210 Esenler, Turkey
[2] Tech Univ Istanbul, Dept Chem, Istanbul, Turkey
来源：
INNOVATIONS IN CHEMICAL BIOLOGY | 2009年
关键词：
Copper; ligand; phenanthroline; thiourea; SODIUM; 1,10-PHENANTHROLINE;
D O I：
10.1007/978-1-4020-6955-0_43
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A new thiourea ligand, N-[1,10-phenanthroline]-N'-[benzo-15-crown-5)yl]thiourea has been synthesized from the reaction of 5-amino-1,10-phenanthroline with 15-isothiocyanatobenzo[15-crown-5] and its Cu(I) complex has been prepared. The structures of the ligand and its complex have been characterized by elemental analysis, UV-vis, F-FIR, H-1 NMR (DMSO-d(6)), C-13 NMR (DMSO-d(6)) and MS spectra (LC-MS).
引用
收藏
页码：367 / +
页数：3
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