Phase Diagrams of Binary Systems Mg(NO3)2-KNO3, Mg(NO3)2-LiNO3 and ternary system Mg(NO3)2-LiNO3-NaNO3

被引：11
|
作者：
Zhong, Yuan [1 ,2 ,3 ]
Yuan, Junsheng [1 ]
Wang, Min [2 ,3 ]
Li, Jinli [2 ,3 ]
机构：
[1] Hebei Univ Technol, Sch Chem Engn & Technol, Tianjin 300130, Peoples R China
[2] Chinese Acad Sci, Key Lab Comprehens & Highly Efficient Utilizat Sa, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
[3] Key Lab Salt Lake Resources Chem Qinghai Prov, Xining 810008, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2020年 / 65卷 / 07期
基金：
中国国家自然科学基金;
关键词：
THERMOPHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES; MOLTEN-SALTS; NANO3; KNO3;
D O I：
10.1021/acs.jced.9b01091
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Phase diagrams of magnesium nitrate-based molten salts were investigated by DSC measurement, including binary systems Mg(NO3)(2)-KNO3, Mg(NO3)(2)-LiNO3, and a portion of ternary system Mg(NO3)(2)-LiNO3-NaNO3. The results show that the melting point of the compound 2KNO(3)center dot Mg(NO3)(2) is found at 223.95 degrees C, and this compound does not have a solid state transition. Mg(NO3)(2)-KNO3 system has two eutectic transitions, one at 177.07 +/- 3 degrees C and the other at 192.51 +/- 1 degrees C for mixtures with 43.00 +/- 1 wt% KNO3 and 70.50 +/- 1 wt% KNO3, respectively; Mg(NO3)(2)-LiNO3 system is a simple eutectic system with one eutectic occurring at 209.23 +/- 1 degrees C for a mixture with 58.00 +/- 1 wt % LiNO3. Mg(NO3)(2)-LiNO3-NaNO3 ternary system has three eutectic curves and one ternary eutectic point at 132.39 +/- 2 degrees C for a mixture with 47.50 +/- 2 wt % Mg(NO3)(2), 13.50 +/- 2 wt % LiNO3, and 39.00 +/- 2 wt % NaNO3.
引用
收藏
页码：3420 / 3427
页数：8
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