Bifunctional Nanoscopic Catalysts for the One-Pot Synthesis of (±)-Menthol from Citral

被引：24
|
作者：
Negoi, Alina [1 ]
Teinz, Katharina [2 ]
Kemnitz, Erhard [2 ]
Wuttke, Stefan [3 ]
Parvulescu, Vasile I. [1 ]
Coman, Simona M. [1 ]
机构：
[1] Univ Bucharest, Fac Chem, Dept Organ Chem Biochem & Catalysis, Bucharest 030016, Romania
[2] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany
[3] Univ Munich LMU, Dept Chem, D-81377 Munich, Germany
来源：
TOPICS IN CATALYSIS | 2012年 / 55卷 / 7-10期
关键词：
Noble metals; Doped nanoscopic fluorides; Sol-gel synthesis; Beta zeolite; Impregnation; Citral; Menthol; LIQUID-PHASE HYDROGENATION; SELECTIVE HYDROGENATION; CARBONYL-ENE; BETA; CITRONELLAL; CYCLIZATION; MENTHOL; STEP; TRANSFORMATION; NANOPARTICLES;
D O I：
10.1007/s11244-012-9850-y
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Active and selective bifunctional Me(Ir, Pd)/beta zeolite and doped nanoscopic hydroxylated fluorides (0.1 % Pd (or Pt)/AlF3) catalysts were developed for the one-pot synthesis of menthols from citral. In the case of fluoride catalysts, the strong electron-withdrawing effect of the dominating fluoride environment depletes the metal surface from electrons and hence, favours the hydrogenation of the C=C bond to citronellal on both Pd and Pt-based catalysts.
引用
收藏
页码：680 / 687
页数：8
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