Development of an efficient solvent free one-pot Heck reaction catalyzed by novel palladium (II) complex-via green approach

被引：24

作者：

Karthikeyan, Parasuraman ^{[1
]}

Muskawar, Prashant Narayan ^{[1
]}

Aswar, Sachin Arunrao ^{[1
]}

Bhagat, Pundlik Rambhau ^{[1
]}

Sythana, Suresh Kumar ^{[1
]}

机构：

[1] VIT Univ, Sch Adv Sci, Div Organ Chem, Vellore 632014, Tamil Nadu, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2012年 / 358卷

关键词：

Palladium complex; Heck reaction; Aryl halide; Alkene; Ambient temperature; ASYMMETRIC ALDOL REACTION; TERT-BUTYL-DICARBONATE; IONIC-LIQUID; ARYL CHLORIDES; ORGANOCATALYST; DERIVATIVES; PROLINE;

D O I：

10.1016/j.molcata.2012.03.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel 1-glycyl-3-methyl imidazolium chloride-palladium (II) complex [[Gmim]Cl-Pd (II)] was found to be a heterogeneous catalyst for an efficient Heck reaction with good to excellent yield under solvent free condition. Tetra-coordinated palladium complex was prepared by reacting PdCl2 with 1-glycyl-3-methyl imidazolium chloride and its catalytic function invented for the C-C bond formation. Spectroscopic evidence of complex has been proved by powder XRD, SEM, FT-IR and AFM. This protocol provides a simple strategy for the generation of a variety of new C-C bonds under environmentally benign condition. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：112 / 120

页数：9

共 35 条

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