Syntheses and properties of cyclometalated ruthenium(II) complexes with 1,10-phenanthroline and phenylphthalazine ligands

被引：5

作者：

Ji, Jiao ^{[1
]}

Li, Guo-Qiang ^{[1
]}

Xu, Ya-Qin ^{[1
]}

Jia, Ai-Quan ^{[1
]}

Zhang, Qian-Feng ^{[1
]}

机构：

[1] Anhui Univ Technol, Inst Mol Engn & Appl Chem, Maanshan 243002, Anhui, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2019年 / 74卷 / 03期

关键词：

1,10-phenanthroline; 1-phenoxy-4-phenyl-phthalazines; crystal structure; cyclometalated complex; phthalazine; ruthenium; CYCLORUTHENATED COMPLEXES;

D O I：

10.1515/znb-2018-0211

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of cis-[RuCl2(phen)(2)] center dot 2H(2)O (phen =1,10-phenanthroline) with 1-(2,6-diisopropyl phenoxy)-4-phenylphthalazine (HL1) or 1-(2,6-dimethylphenoxy)-4-phenylphthalazine (HL2) in the presence of AgPF6 afforded two cyclometalated ruthenium(II) complexes, [Ru(kappa(2)-C,N-L1)(phen)(2)](PF6) (1) and [Ru(kappa(2)-C,N-L2)(phen)(2)](PF6) (2), respectively. The two complexes have been characterized by UV-vis and luminescence spectroscopy. The structure of 1.1.5H(2)O has been determined by single-crystal X-ray diffraction.

引用

页码：267 / 271

页数：5

共 22 条

[1] DESIGNED SYNTHESIS OF MONONUCLEAR TRIS(HETEROLEPTIC) RUTHENIUM COMPLEXES CONTAINING BIDENTATE POLYPYRIDYL LIGANDS [J].

ANDERSON, PA ;

DEACON, GB ;

HAARMANN, KH ;

KEENE, FR ;

MEYER, TJ ;

REITSMA, DA ;

SKELTON, BW ;

STROUSE, GF ;

THOMAS, NC ;

TREADWAY, JA ;

WHITE, AH .

INORGANIC CHEMISTRY, 1995, 34 (24) :6145-6157

[2]

[Anonymous], 1996, SADABS

[3]

[Anonymous], 1998, SMART SAINT WIND NT

[4]

Baratta W., 2005, ANGEW CHEM INT ED, V44

[5] Cyclometalated ruthenium chromophores for the dye-sensitized solar cell [J].

Bomben, Paolo G. ;

Robson, Kiyoshi C. D. ;

Koivisto, Bryan D. ;

Berlinguette, Curtis P. .

COORDINATION CHEMISTRY REVIEWS, 2012, 256 (15-16) :1438-1450

[6] Modular synthesis of simple cycloruthenated complexes with state-of-the-art performance in p-type DSCs [J].

Brunner, Felix ;

Marinakis, Nathalie ;

Wobill, Cedric ;

Willgert, Markus ;

Ertl, Cathrin D. ;

Kosmalski, Tatjana ;

Neuburger, Markus ;

Bozic-Weber, Biljana ;

Glatzel, Thilo ;

Constable, Edwin C. ;

Housecroft, Catherine E. .

JOURNAL OF MATERIALS CHEMISTRY C, 2016, 4 (41) :9823-9833

[7] Cycloruthenated Complexes from Imine-Based Heterocycles: Synthesis, Characterization, and Reactivity toward Alkynes [J].

Cuesta, Luciano ;

Soler, Tatiana ;

Urriolabeitia, Esteban P. .

CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (47) :15178-15189

[8] Sticking and patching: tuning and anchoring cyclometallated ruthenium(II) complexes [J].

Ertl, Cathrin D. ;

Ris, Daniel P. ;

Meier, Stefan C. ;

Constable, Edwin C. ;

Housecroft, Catherine E. ;

Neuburger, Markus ;

Zampese, Jennifer A. .

DALTON TRANSACTIONS, 2015, 44 (04) :1557-1570

[9] The Fate of Cycloruthenated Compounds: From C-H Activation to Innovative Anticancer Therapy [J].

Gaiddon, Christian ;

Pfeffer, Michel .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (12) :1639-1654

[10] Synthesis and X-ray crystal structure of a bis-cyclometalated phosphorescent red-emitting iridium(III) complex [J].

Graf, Marion ;

Thesen, Manuel ;

Krueger, Hartmut ;

Mayer, Peter ;

Suenkel, Karlheinz .

INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (08) :701-703

← 1 2 3 →