Assessment of flame retardants in river water using a ceramic dosimeter passive sampler

被引：43
作者：
Cristale, Joyce [2 ]
Katsoyiannis, Athanasios [1 ,3 ]
Chen, Chang'er [1 ]
Jones, Kevin C. [1 ]
Lacorte, Silvia [2 ]
机构：
[1] Univ Lancaster, Lancaster Environm Ctr, Lancaster LA1 4YQ, England
[2] CSIC, Dept Environm Chem, IDAEA, ES-08034 Barcelona, Catalonia, Spain
[3] FRAM High N Res Ctr Climate & Environm, NILU, NO-9296 Tromso, Norway
来源：
ENVIRONMENTAL POLLUTION | 2013年 / 172卷
关键词：
Ceramic dosimeter; Passive sampler; Organophosphorous flame retardants; Brominated flame retardants; River water; ORGANIC POLLUTANTS POPS; SURFACE WATERS; IN-SITU; ORGANOPHOSPHORUS; SNOW;
D O I：
10.1016/j.envpol.2012.08.014
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Novel brominated (BFRs) and organophosphorus (OPFRs) flame retardants were monitored in river water using the ceramic dosimeter passive sampling device with HLB (hydrophilic lipophilic balance) as sorbent. Laboratory calibrations were performed to determine sampling rates for each compound using the Archie's law exponent. The passive sampling device was used to determine the presence of 6 BFRs in the River Aire (United Kingdom), selected according to their ubiquitous presence in the River Aire. Passive sampling integrated river water concentrations ranged from 0.010 to 5.6 mu g L-1 for all OPFRs, while BFRs were not detected with this specific passive sampler configuration. Decreased sampling rates were evidenced after 3 weeks of deployment, probably due to fouling. Good agreement between integrated and snapshot water concentrations was obtained, indicating the efficiency of the passive sampler for the monitoring of OPFRs in river water. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：163 / 169
页数：7
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