Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu)

被引：603
作者：
Zheng, Shou-Tian [1 ]
Yang, Guo-Yu [1 ,2 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Beijing Inst Technol, Sch Chem, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China
来源：
CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 22期
关键词：
TRANSITION-METAL CLUSTERS; FERROMAGNETIC EXCHANGE INTERACTIONS; WELLS-DAWSON HETEROPOLYTUNGSTATES; INELASTIC NEUTRON-SCATTERING; MULTI-IRON SILICOTUNGSTATES; SANDWICH-TYPE POLYOXOANIONS; SINGLE-MOLECULE MAGNET; X-RAY CHARACTERIZATION; HYDROTHERMAL CONDITIONS; CRYSTAL-STRUCTURE;
D O I：
10.1039/c2cs35133a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
During the past decade, research into transition-metal-substituted polyoxometalate self-assembly has been greatly developed. This review summarizes the conventional solution syntheses and hydrothermal syntheses of novel substituted polyoxometalates based on the incorporation of paramagnetic transition metals Mn, Fe, Co, Ni, and Cu, with an emphasis on the variety of nuclearities and configurations of encapsulated transition metal cores and the rich architectures of overall polyoxometalates.
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收藏
页码：7623 / 7646
页数：24
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