Chameleon Luminophore for Sensing Temperatures: Control of Metal-to-Metal and Energy Back Transfer in Lanthanide Coordination Polymers

被引：317

作者：

Miyata, Kohei ^{[1
]}

Konno, Yuji ^{[3
]}

Nakanishi, Takayuki ^{[1
]}

Kobayashi, Atsushi ^{[2
]}

Kato, Masako ^{[2
]}

Fushimi, Koji ^{[1
]}

Hasegawa, Yasuchika ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Sapporo, Hokkaido 0608628, Japan

[2] Hokkaido Univ, Grad Sch Sci, Sapporo, Hokkaido 0600810, Japan

[3] Asahikawa Natl Coll Technol, Asahikawa, Hokkaido 0718142, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 25期

关键词：

dyes; lanthanides; luminescence; metal-organic frameworks; phosphane ligands; EU(III) COMPLEX; HIGHLY LUMINESCENT; LIGANDS; SENSORS; PROBE;

D O I：

10.1002/anie.201301448

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chameleon luminophore: A temperature-sensing material is reported that has a high thermostability (see picture). The material is composed of color-changing luminescent coordination polymers containing EuIII and TbIII ions. The coordination polymer exhibits a high emission quantum yield Φ of 40 % at room temperature and a temperature-sensing ability over a wide range of 200-500 K. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6413 / 6416

页数：4

共 32 条

[1] Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations [J].

An, Jihyun ;

Shade, Chad M. ;

Chengelis-Czegan, Demetra A. ;

Petoud, Stephane ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1220-1223

[2]

[Anonymous], 2003, P MOSAIC INT WORKSH

[3] Lanthanide-Based Luminescent Hybrid Materials [J].

Binnemans, Koen .

CHEMICAL REVIEWS, 2009, 109 (09) :4283-4374

[4]

BLASSE G, 1994, LUMINESCENT MAT, P92

[5] Lanthanide Luminescence for Biomedical Analyses and Imaging [J].

Buenzli, Jean-Claude G. .

CHEMICAL REVIEWS, 2010, 110 (05) :2729-2755

[6] Progress on lanthanide-based organic-inorganic hybrid phosphors [J].

Carlos, Luis D. ;

Ferreira, Rute A. S. ;

Bermudez, Veronica de Zea ;

Julian-Lopez, Beatriz ;

Escribano, Purificacion .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (02) :536-549

[7] New Trick for an Old Ligand! The Sensing of Zn(II) Using a Lanthanide Based Ternary Yb(III)-cyclen-8-hydroxyquinoline System As a Dual Emissive Probe for Displacement Assay [J].

Comby, Steve ;

Tuck, Sarah A. ;

Truman, Laura K. ;

Kotova, Oxana ;

Gunnlaugsson, Thorfinnur .

INORGANIC CHEMISTRY, 2012, 51 (19) :10158-10168

[8] Highly Luminescent and Triboluminescent Coordination Polymers Assembled from Lanthanide β-Diketonates and Aromatic Bidentate O-Donor Ligands [J].

Eliseeva, Svetlana V. ;

Pleshkov, Dmitry N. ;

Lyssenko, Konstantin A. ;

Lepnev, Leonid S. ;

Buenzli, Jean-Claude G. ;

Kuzminat, Natalia P. .

INORGANIC CHEMISTRY, 2010, 49 (20) :9300-9311

[9] Lanthanide luminescence for functional materials and bio-sciences [J].

Eliseeva, Svetlana V. ;

Buenzli, Jean-Claude G. .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :189-227

[10] pH Dependent self-assembly of dimetallic lanthanide complexes [J].

Faulkner, S ;

Burton-Pye, BP .

CHEMICAL COMMUNICATIONS, 2005, (02) :259-261

← 1 2 3 4 →