Directive effects in the hydroboration of 1-alkenyl derivatives of o-carborane with representative hydroborating agents

被引：6

作者：

Kabalka, GW ^{[1
]}

Hondrogiannis, G ^{[1
]}

机构：

[1] UNIV TENNESSEE,DEPT RADIOL,KNOXVILLE,TN 37996

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 536卷 / 1-2期

关键词：

hydroboration; alkenylcarboranes; o-carborane; borane-THF; boron;

D O I：

10.1016/S0022-328X(96)06695-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of 1-alkenyl-o-carboranes was hydroborated using representative hydroborating agents with different steric requirements. The steric and electronic effects of the carboranyl group were evaluated by examining the distribution of the isomeric alcohols obtained after oxidation of the intermediate carboranyl-substituted organoboranes. (C) 1997 Elsevier Science S.A.

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页码：327 / 337

页数：11

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