Isobaric Vapor-Liquid Equilibrium for Two Binary Systems, (3-Methyl-1-butanol+1,4-Butanediol) and (Hexylene Glycol+1,4-Butanediol), at p=40.0, 60.0, and 80.0 kPa

被引:1
作者
Zhi, Juan [1 ]
Jin, Fengmin [1 ]
Yang, Qian [1 ]
Feng, Xue [1 ]
Yang, Changsheng [1 ]
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, State Educ Minist, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China
关键词
N; N-DIETHYLETHANOLAMINE; 1,4-BUTANEDIOL; DIETHYLAMINE; EXPRESSION; MIXTURES; ENERGY; ETHYL;
D O I
10.1021/acs.jced.6b00092
中图分类号
O414.1 [热力学];
学科分类号
摘要
The isobaric vaporliquid equilibrium data for the two binary systems of (3-methyl-1-butanol + 1,4-butanediol, hexylene glycol + 1,4-butanediol) at p = 40.0, 60.0, and 80.0 kPa were obtained by a improved Rose equilibrium still. The thermodynamic consistency of the VLE (vaporliquid equilibrium) data was checked via the methods of the Herington area test and the Van Ness point test. In addition, the nonrandom two-liquid (NRTL), Wilson, and universal quasichemical (UNIQUAC) activity coefficient models were adopted to correlate the VLE data. The calculated values of the models mentioned above showed good agreements with the measured data.
引用
收藏
页码:3041 / 3047
页数:7
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