Biodiesel from Waste Cooking Oil via Heterogeneous Superacid Catalyst SO42-/ZrO2

被引：99
作者：
Fu, Baosong [1 ]
Gao, Lijing [1 ]
Niu, Lei [1 ]
Wei, Reiping [1 ]
Xiao, Guomin [1 ]
机构：
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
来源：
ENERGY & FUELS | 2009年 / 23卷 / 1-2期
关键词：
SULFATED ZIRCONIA; SOYBEAN OIL; POULTRY FAT; TRANSESTERIFICATION; OPTIMIZATION; DESIGN;
D O I：
10.1021/ef800751z
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The solid superacid catalyst SO42-/ZrO2 was prepared by impregnation and characterized by infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction. Their performances were evaluated by the transesterification reaction of waste cooking oil (WCO) with methanol. The influence of the load ratio of SO42-/ZrO2, molar ratio of methanol/waste cooking oil, catalyst amount, reaction temperature, and reaction time on biodiesel yield was investigated. Under a condition of methanol/WCO molar ratio of 9:1, a catalyst amount of 3 wt %, reaction time of 4 h, and reaction temperature of 120 degrees C, 93.6% of biodiesel yield was obtained.
引用
收藏
页码：569 / 572
页数：4
相关论文
共 25 条
[1]   Liquid-phase catalytic activity of sulfated zirconia from sol-gel precursors: the role of the surface features [J].
Ardizzone, S ;
Bianchi, CL ;
Cappelletti, G ;
Porta, F .
JOURNAL OF CATALYSIS, 2004, 227 (02) :470-478
[2]   Transesterification of palm oil with methanol to biodiesel over a KF/Al2O3 heterogeneous base catalyst [J].
Bo, Xu ;
Xiao, Guomin ;
Cui, Lingfeng ;
Wei, Ruiping ;
Gao, Lijing .
ENERGY & FUELS, 2007, 21 (06) :3109-3112
[3]   Structure-reactivity correlations in MgAl hydrotalcite catalysts for biodiesel synthesis [J].
Cantrell, DG ;
Gillie, LJ ;
Lee, AF ;
Wilson, K .
APPLIED CATALYSIS A-GENERAL, 2005, 287 (02) :183-190
[4]   Biodiesel production from crude palm oil and evaluation of butanol extraction and fuel properties [J].
Crabbe, E ;
Nolasco-Hipolito, C ;
Kobayashi, G ;
Sonomoto, K ;
Ishizaki, A .
PROCESS BIOCHEMISTRY, 2001, 37 (01) :65-71
[5]   Transesterification of cottonseed oil to biodiesel by using heterogeneous solid basic catalysts [J].
Cui Lingfeng ;
Xiao Guomin ;
Xu Bo ;
Teng Guangyuan .
ENERGY & FUELS, 2007, 21 (06) :3740-3743
[6]   Transesterification reaction of vegetable oils, using superacid sulfated TiO2-base catalysts [J].
de Almeida, Rusiene M. ;
Noda, Lucia K. ;
Goncalves, Norberto S. ;
Meneghetti, Simoni M. P. ;
Meneghetti, Mario R. .
APPLIED CATALYSIS A-GENERAL, 2008, 347 (01) :100-105
[7]   Transesterification of soybean oil to biodiesel by using heterogeneous basic catalysts [J].
Di Serio, M ;
Ledda, M ;
Cozzolino, M ;
Minutillo, G ;
Tesser, R ;
Santacesaria, E .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (09) :3009-3014
[8]  
FREEDMAN B, 2000, J AM OIL CHEM SOC, V77, P1263
[9]   Transesterfication of soybean oil catalyzed by sulfated ziconia [J].
Garcia, Camila Martins ;
Teixeira, Sergio ;
Marciniuk, Leticia Ledo ;
Schuchardt, Ulf .
BIORESOURCE TECHNOLOGY, 2008, 99 (14) :6608-6613
[10]   Solid acid catalysts for biodiesel production - Towards sustainable energy [J].
Kiss, AA ;
Dimian, AC ;
Rothenberg, G .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (1-2) :75-81
123