A study of 4-carboxyphenylboronic acid as a corrosion inhibitor for steel in carbon dioxide containing environments

被引:104
作者
Nam, N. D. [1 ]
Bui, Q. V. [2 ]
Mathesh, M. [3 ]
Tan, M. Y. J. [1 ]
Forsyth, M. [1 ]
机构
[1] Deakin Univ, Inst Frontier Mat, Geelong, Vic 3220, Australia
[2] Sungkyunkwan Univ, Dept Adv Mat Sci & Engn, Suwon 440746, South Korea
[3] Deakin Univ, Sch Life & Environm Sci, Geelong, Vic 3220, Australia
关键词
Steel; EIS; Polarization; Acid corrosion; Acid inhibition; MILD-STEEL; ACETIC-ACID; IMPEDANCE SPECTROSCOPY; POURBAIX DIAGRAM; CO2; CORROSION; GREEN RUST; RESISTANCE; MECHANISM; HYDROXIDE; ARGINASE;
D O I
10.1016/j.corsci.2013.06.048
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
4-Carboxyphenylboronic acid (CPBA) has been found to be an efficient carbon dioxide (CO2) corrosion inhibitor for steel in aqueous media. The results indicate that the addition of CPBA to CO2 containing sodium chloride solutions at a low concentration is able to retard corrosion anodic reactions, reduce corrosion current densities, increase charge transfer and total resistances, resulting in more uniform and smoother steel surfaces. These effects are attributed to the formation of a barrier layer on steel surface, which provides metal surface protection. The inhibitor was also found to mitigate corrosion by promoting random distribution of minor anodes. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:257 / 266
页数:10
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