The Active Transport of Ions of Rare-Earth Elements, Alkali Metals, Al(III), and Mg(II) with New Lipophilic N,N-Bis[(Dihexylphosphoryl)Methyl]Octylamine
被引:7
作者:
Davletshina, Natal'ya
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机构:
Kazan Fed Univ, AM Butlerov Chem Inst, Kazan 420008, Tatarstan, RussiaKazan Fed Univ, AM Butlerov Chem Inst, Kazan 420008, Tatarstan, Russia
Davletshina, Natal'ya
[1
]
Garifzyanov, Airat
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机构:
Kazan Fed Univ, AM Butlerov Chem Inst, Kazan 420008, Tatarstan, RussiaKazan Fed Univ, AM Butlerov Chem Inst, Kazan 420008, Tatarstan, Russia
Garifzyanov, Airat
[1
]
Cherkasov, Rafael
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机构:
Kazan Fed Univ, AM Butlerov Chem Inst, Kazan 420008, Tatarstan, RussiaKazan Fed Univ, AM Butlerov Chem Inst, Kazan 420008, Tatarstan, Russia
Cherkasov, Rafael
[1
]
机构:
[1] Kazan Fed Univ, AM Butlerov Chem Inst, Kazan 420008, Tatarstan, Russia
Active transport;
aminophosphine oxide;
rare earth;
D O I:
10.1080/10426507.2012.740691
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
The Active Transport of Ions of Rare-Earth Elements, Alkali Metals, Al(III) and Mg(II) with N,N- Bis[(dihexylphosphoryl)methyl]octylamine was studied. It is found that with the selected reagent the flow of ions S?(III) and Nd(III) is several times higher than the flow of ions Al(III) and Mg(II). Also, the mixtures of bis(aminophosphoryl) reagent and mono-/dithiophosphoric acids show evidence for synergistic effects with high selectivity when used for the extraction of Li(I).