Efficient synthesis of sulfonyl azides from sulfonamides

被引：41

作者：

Raushel, Jessica ^{[1
]}

Pitram, Suresh M. ^{[1
]}

Fokin, Valery V. ^{[1
]}

机构：

[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 16期

关键词：

D O I：

10.1021/ol8011088

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Triflyl azide serves as an efficient diazo transfer reagent in this first direct synthesis of sulfonyl azides from readily available and stable sulfonamides. The process is experimentally simple, mild, and high-yielding. Sulfonyl azides participate in various catalytic transformations providing rapid access to diversely functionalized sulfonamide derivatives in good yields.

引用

页码：3385 / 3388

页数：4

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