Syntheses, crystal structures, and fluorescent properties of two d10 metal complexes based on 2-(benzoimidazol-yl)methyl)-1H-1,2,4-triazole and 1,3,5-benzenetricarboxylate

被引：14

作者：

Liu, Bingtao ^{[1
]}

Wang, Rui ^{[2
]}

Jin, Guanghua ^{[2
]}

Meng, Xiangru ^{[2
]}

机构：

[1] North China Inst Water Conservancy & Hydroelect P, Sch Environm & Municipal Engn, Zhengzhou, Peoples R China

[2] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 10期

基金：

中国国家自然科学基金;

关键词：

2-((Benzoimidazol-yl)methyl)-1H-1; 2; 4-triazole; Crystal structure; d(10)-Metal complexes; Fluorescent property; Thermostability; COORDINATION POLYMERS; ORGANIC FRAMEWORKS; AROMATIC POLYCARBOXYLATE; LUMINESCENT PROPERTIES; CADMIUM(II) COMPLEXES; LAYER; COBALT(II); ZINC(II); DESIGN; LIGAND;

D O I：

10.1080/00958972.2013.790017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two d(10) metal complexes, {[Zn(Hbtc)(bmt)]center dot DMF center dot 5H(2)O} (n) (1) and {[Cd(Hbtc)(bmt)]center dot 0.5DMF center dot 0.5H(2)O} (n) (2) (H(3)btc=1,3,5-benzenetricarboxylic acid, bmt=2-((benzoimidazol-yl)methyl)-1H-1,2,4-triazole), have been synthesized under solvothermal conditions by employing bmt and H(3)btc. Single-crystal X-ray diffraction shows that Zn(II) ions are connected by bmt with bidentate-bridging coordination and by 1,3,5-benzenetricarboxylate with bis-monodentate coordination leading to the 2D structure of 1. Complex 2 exhibits a 2D layer structure, in which bmt coordinate tridentate-bridging to Cd(II) and 1,3,5-benzenetricarboxylates coordinate to Cd(II) unidentate/chelating. Photoluminescence and thermogravimetric analyses of the two complexes are investigated.

引用

页码：1784 / 1794

页数：11

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