Morphology and activity of vanadium-containing catalysts for the selective oxidation of benzene to maleic anhydride

被引：2

作者：

Dosumov, K. ^{[1
]}

Ergazieva, G. E. ^{[2
]}

机构：

[1] Al Farabi Kazakh Natl Univ, Ctr Physicochem Methods Res & Anal, Alma Ata 050012, Kazakhstan

[2] DV Sokolskii Organ Catalysis & Electrochem Inst, Alma Ata 050012, Kazakhstan

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2012年 / 86卷 / 11期

关键词：

benzene oxidation; maleic anhydride; vanadium-containing catalyst;

D O I：

10.1134/S0036024412110106

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The morphology and activity of vanadium catalysts are studied using a number of physicochemical methods: electron microscopy, electron paramagnetic resonance, and infrared spectroscopy. It is found that the active agent of the conversion of benzene to maleic anhydride over modified vanadium catalysts is the V4+ ion in the vanadyl configuration.

引用

页码：1766 / 1768

页数：3

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