Allylic alcohols as radical allylating agents. An overall olefination of aldehydes and ketones

被引：37
|
作者：
Charrier, Nicolas [1 ]
Quiclet-Sire, Beatrice [1 ]
Zard, Samir Z. [1 ]
机构：
[1] Ecole Polytech, CNRS, Synth Organ Lab, UMR 7652, F-91128 Palaiseau, France
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 28期
关键词：
D O I：
10.1021/ja802899m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
2-Fluoroyridynl derivatives of allylic alcohols react with xanthates in the presence of lauroyl peroxide to give alkenes, often with high stereoselectivity. If the allylic alcohols are themselves derived from aldehydes or ketones, the overall process becomes a synthetic equivalent of the classical Witting and related olefination reactions.
引用
收藏
页码：8898 / +
页数：3
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