Bis(triethanolamine-κ3N,O,O′)nickel(II) benzene-1,4-dicarboxylate

被引：22

作者：

Haukka, M ^{[1
]}

Kirillov, AM

Kopylovich, MN

Pombeiro, AJL

机构：

[1] Univ Joensuu, Dept Chem, POB 111, FIN-80101 Joensuu, Finland

[2] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805039127

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Ni(C6H15NO3)(2)](C8H4O4), consists of a [Ni(H(3)tea)(2)](2+) cation (H(3)tea is triethanolamine) and a benzene-1,4-dicarboxylate (terephthalate) anion. The Ni-II atom lies on an inversion centre and exhibits a slightly distorted octahedral coordination geometry formed by two molecules of H3tea acting as N,O,O'-tridentate ligands; the anion is also centrosymmetric. All the OH groups of H(3)tea are involved in an O-H center dot center dot center dot O hydrogen-bonding network with terephthalate O atoms, thus linking the molecular units in chains and forming a two-dimensional infinite network.

引用

页码：M2746 / M2748

页数：3

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