An experimental method for the determination of metal-polymer adhesion

被引：17

作者：

Gasparin, A. L. ^{[1
]}

Wanke, C. H. ^{[2
]}

Nunes, R. C. R. ^{[3
]}

Tentardini, E. K. ^{[4
]}

Figueroa, C. A. ^{[1
]}

Baumvol, I. J. R. ^{[1
,2
]}

Oliveira, R. V. B. ^{[2
]}

机构：

[1] Univ Caxias do Sul, Caxias Do Sul, Brazil

[2] Univ Fed Rio Grande do Sul, BR-91509900 Porto Alegre, RS, Brazil

[3] Univ Fed Rio de Janeiro, Rio De Janeiro, Brazil

[4] Univ Fed Sergipe, BR-49100000 Aracaju, Brazil

来源：

THIN SOLID FILMS | 2013年 / 534卷

关键词：

Metal-polymer interface; Adhesion strength; Cohesion; Surface treatment; THIN COPPER-FILMS; SURFACE MODIFICATION;

D O I：

10.1016/j.tsf.2013.03.018

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A method is proposed in order to reduce significantly the influence of the coating shear stress and its cohesion failure on the normal adhesion stress of metallic films on polymers. Most methods used so far were not able to avoid the interference of the cohesion failure when the interface was delaminated in order to measure the adhesion strength. Our method has been proved to work and the results are more accurate than the standard pull-off method. The experiments consisted in delaminating copper films deposited by physical vapor deposition on four different kinds of polymeric substrates: polypropylene, polyamide 6, high impact polystyrene and polyethylene terephthalate. The polymer surfaces have also been modified by means of substrate sanding and flaming processes. Optical and scanning electron microscopies were used to study the morphology of both the removed copper film and the polymer surface after pulling-off. Adhesion work was measured by contact angle to determine the necessary energy to pull-off the metal-polymer interface. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：356 / 362

页数：7

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