Tandem Hydroformylation/Hydrogenation of Alkenes to Normal Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst

被引：112
|
作者：
Takahashi, Kohei [1 ]
Yamashita, Makoto [1 ]
Nozaki, Kyoko [1 ]
机构：
[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 45期
基金：
日本学术振兴会;
关键词：
CARBON-DIOXIDE; BIPHASIC HYDROFORMYLATION; HYDROGENATION CATALYST; RUTHENIUM COMPLEXES; LINEAR ALCOHOLS; RHODIUM; LIGANDS; WATER; OLEFINS; HYDRIDE;
D O I：
10.1021/ja307998h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The catalyst system: for tandem hydroformylation/hydrogenation of terminal alkenes to the corresponding homologated normal alcohol was developed The reaction mechanism for the Rh/Ru dual catalyst was investigated by real-time IR monitoring experiments and P-31 NMR spectroscopy, which proved the mutual orthogonality of Rh-catalyzed hidroformylation and Ru-catalyzed hydrogenation. Detailed investigation about Ru-catalyzed hydrogenation of undecanal under H-2/CO pressure clarified different kinetics from the hydrogenation under H-2 and gave a clue to design more active hydrogenation catalysts under H-2/CO atmosphere. The solely Ru-catalyzed normal selective hydroformylation/hydrogenation is also reported.
引用
收藏
页码：18746 / 18757
页数：12
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