Fabrication and microstructure of p-type transparent conducting CuS thin film and its application in dye-sensitized solar cell

被引:116
作者
Yuan, K. D. [1 ]
Wu, J. J. [1 ]
Liu, M. L. [1 ]
Zhang, L. L. [1 ]
Xu, F. F. [1 ]
Chen, L. D. [1 ]
Huang, F. Q. [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2991441
中图分类号
O59 [应用物理学];
学科分类号
摘要
By reducing film thickness to a few nanometers, the narrow-band-gap CuS turns highly transparent. Surface modification by a self- assembled monolayer is the key factor to obtain a thin, dense, and continuous film. The film growth mechanism is identified as "layer-by-layer growth followed by islanding." After annealing, a p-type conductivity of similar to 2 x 10(3) S cm(-1) is achieved at room temperature, and the thinnest conductive film has an average transparency of 92% between 400 and 800 nm. Using p-type CuS films as front contact layers, a dye-sensitized solar cell was fabricated with a significant photoelectric response. (C) 2008 American Institute of Physics.
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页数:3
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