Selective hydrogen absorption from gaseous mixtures by BCC Ti-V alloys

被引：24

作者：

Suwarno, S. ^{[2
]}

Gosselin, Y. ^{[1
]}

Solberg, J. K. ^{[2
]}

Maehlen, J. P. ^{[1
]}

Williams, M. ^{[4
]}

Krogh, B. ^{[3
]}

Borresen, B. T. ^{[3
]}

Rytter, E. ^{[3
]}

Ochoa-Fernandez, E. ^{[3
]}

Yartys, V. A. ^{[1
,2
]}

机构：

[1] Inst Energy Technol, NO-2027 Kjeller, Norway

[2] NTNU, Dept Mat Sci & Engn, NO-7491 Trondheim, Norway

[3] Statoil Res Ctr, N-7005 Trondheim, Norway

[4] Univ Western Cape, Dept Chem, S African Inst Adv Mat Chem, ZA-7535 Bellville, South Africa

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2012年 / 37卷 / 05期

关键词：

Hydrogen production; Steam reforming; Metal hydrides; Titanium; Vanadium; Synchrotron X-ray diffraction; SURFACE-PROPERTIES; IMPURE HYDROGEN; STORAGE ALLOYS; METAL-HYDRIDES; LANI5; MAGNESIUM; PURIFICATION; REFINEMENT; POWDER; FETI;

D O I：

10.1016/j.ijhydene.2011.11.100

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen absorption behaviour of the BCC Ti-V alloys has been studied as related to their potential application for the selective hydrogen absorption from mixtures with active gases containing CO and steam at high temperatures. Alloys and their hydrides were characterised using Scanning Electron Microscopy (SEM), Thermal Desorption Spectroscopy (TDS), Temperature Programmed Reaction (TPR) and in situ synchrotron X-ray powder diffraction (SR-XRD). BCC Ti0.8V0.2 and Ti0.9V0.1 were able to absorb 3.95 wt.% H by forming a FCC type hydride gamma-(Ti,V)H-2. Nanoparticles of Pd and Pd/Pt were electroless deposited on the surface of the hydrides to catalyse hydrogen absorption. TPR tests showed that such alloys were capable of absorbing hydrogen even when substantial amounts of CO and H2O were present in the gas stream. Nanoparticles of Pd/Pt provide a better performance as compared to Pd alone. In situ SR-XRD has been used to probe the mechanisms of hydrogenation and dehydrogenation. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：4127 / 4138

页数：12

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