Microwave Spectrum of N-Methylformamide

被引:0
|
作者
Meshcheryakov, A. A. [1 ,2 ]
Ilyushin, V. V. [1 ,2 ]
Alekseev, E. A. [1 ,2 ]
Motienko, R. A. [3 ]
Margules, L. [3 ]
机构
[1] NASU, Inst Radio Astron, Microwave Spect Dept, Kharkov, Ukraine
[2] Kharkov Natl Univ, Quantum Radiophys Dept, Kharkov, Ukraine
[3] Univ Lille 1, Lab Phys Lasers Atomes & Mol, Villeneuve Dascq, France
来源
2016 9TH INTERNATIONAL KHARKIV SYMPOSIUM ON PHYSICS AND ENGINEERING OF MICROWAVES, MILLIMETER AND SUBMILLIMETER WAVES (MSMW) | 2016年
关键词
N-methylformamide; microwave spectrum; methyl top internal rotation; ROTATIONAL SPECTRUM; SPECTROSCOPY; MOLECULE;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Rotational spectra of the N-methylformamide HCONHCH3 molecule were recorded in the frequency range between 45 and 630 GHz. Analysis was carried out for the trans conformer of the molecule using the Rho axis method where the quadrupole hyperfine structure was taken into account in the first order of perturbation treatment. The analysed dataset for trans conformer contains 18914 A and E transitions with J <= 62 in the ground, first, and second excited torsional states. A fit within experimental error is achieved with weighted root-mean-square deviation of 0.85.
引用
收藏
页数:4
相关论文
共 50 条
  • [21] Rotational spectroscopy, tentative interstellar detection, and chemical modeling of N-methylformamide
    Belloche, A.
    Meshcheryakov, A. A.
    Garrod, R. T.
    Ilyushin, V. V.
    Alekseev, E. A.
    Motiyenko, R. A.
    Margules, L.
    Mueller, H. S. P.
    Menten, K. M.
    ASTRONOMY & ASTROPHYSICS, 2017, 601
  • [22] Correlation times and quadrupole coupling constants in liquid N-methylformamide and N-methylacetamide
    Seipelt, CG
    Zeidler, MD
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1997, 101 (10): : 1501 - 1508
  • [23] PHASE-II TRIAL OF N-METHYLFORMAMIDE IN LUNG-CANCER
    CODY, RL
    SEID, JE
    NATALE, RB
    INVESTIGATIONAL NEW DRUGS, 1992, 10 (03) : 215 - 216
  • [24] A comparison of micelle formation of ionic surfactants in formamide, in N-methylformamide and in N,N-dimethylformamide
    Akhter, MS
    Alawi, SM
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2003, 219 (1-3) : 281 - 290
  • [25] Influencing parameters of direct homogenization intercalation of kaolinite with urea, dimethyl sulfoxide, formamide, and N-methylformamide
    Mako, Eva
    Kovacs, Andras
    Kristof, Tamas
    APPLIED CLAY SCIENCE, 2019, 182
  • [26] N-methylformamide induces multiple organ toxicity in Fischer 344 rats
    Mi Ju Lee
    Hyo-Geun Cha
    Ka Young Park
    Yong-Soon Kim
    Byeongwoo Ahn
    Toxicological Research, 2023, 39 : 263 - 274
  • [27] Photo-stability of peptide-bond aggregates: N-methylformamide dimers
    Crespo-Otero, Rachel
    Mardykov, Artur
    Sanchez-Garcia, Elsa
    Sander, Wolfram
    Barbatti, Mario
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (35) : 18877 - 18887
  • [28] Interactions of transition metal ions with N-methylformamide as a peptide bond model system
    Vranes, Milan
    Papovic, Snezana
    Rodic, Marko
    Jovic, Branislav
    Belic, Sanja
    Gadzuric, Slobodan
    JOURNAL OF MOLECULAR LIQUIDS, 2019, 284 : 405 - 414
  • [29] Enhancement of antitumor activity of the oxazaphosphorine cytostatic SUM-IAP by N-methylformamide
    Voelcker, G.
    JOURNAL OF CANCER RESEARCH AND CLINICAL ONCOLOGY, 2016, 142 (06) : 1183 - 1189
  • [30] Dielectric relaxation spectroscopy of ion-solvent interactions in formamide and N-methylformamide
    Wurm, Bernhard
    Baar, Christian
    Buchner, Richard
    Barthel, Josef
    JOURNAL OF MOLECULAR LIQUIDS, 2006, 127 (1-3) : 14 - 20