Synthesis and characterization of a new vanadium oxide, TMAV(8)O(20)

被引：49

作者：

Chirayil, T ^{[1
]}

Zavalij, PY ^{[1
]}

Whittingham, MS ^{[1
]}

机构：

[1] SUNY BINGHAMTON,CTR MAT RES,BINGHAMTON,NY 13902

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1997年 / 7卷 / 11期

关键词：

D O I：

10.1039/a704624c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrothermal synthesis of V2O5 + TMA + LIOH in a 1:2:1 molar ratio after adjusting the pH with acetic acid to pH 3.3 resulted in the formation of a new vanadium oxide, TMAV(8)O(20). The new vanadium oxide has a monoclinic structure with space group C2/m and lattice parameters: a = 23.655(2), b = 3.5931(3), c = 6.3175(5) Angstrom and beta = 103.060(4)degrees. TMAV(8)O(20) has a layered structure with the vanadium atom in the octahedral sites and tetramethylammonium ions residing in between the vanadium layers.

引用

页码：2193 / 2195

页数：3

共 27 条

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