Quantification of electron transfer rates of different facets on single gold nanoparticles during catalytic reactions

被引：35

作者：

Eo, Moonjung ^{[1
]}

Baek, Jayeon ^{[1
]}

Song, Hyeon Don ^{[1
]}

Lee, Suseung ^{[1
]}

Yi, Jongheop ^{[1
]}

机构：

[1] Seoul Natl Univ, Coll Engn, Sch Chem & Biol Engn, Inst Chem Proc,World Class Univ Program Chem Conv, Seoul 151742, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 45期

基金：

新加坡国家研究基金会;

关键词：

HIGH-INDEX FACETS; PLATINUM NANOCRYSTALS; AQUEOUS-SOLUTION; 4-NITROPHENOL; SPECTROSCOPY; REDUCTION;

D O I：

10.1039/c3cc41627e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rayleigh scattering spectra of high-index {730} elongated tetrahexahedral gold nanoparticles and low-index {100}, {110}, and {111} gold nanorods were collected in real time in the reduction of 4-nitrophenol. The high-index facets are capable of accepting electrons seven times faster and emitting electrons two-and-a-half times faster than low-index facets.

引用

页码：5204 / 5206

页数：3

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