MIL-100(Fe)-catalyzed efficient conversion of hexoses to lactic acid

被引：88

作者：

Huang, Shan ^{[1
]}

Yang, Kai-Li ^{[1
]}

Liu, Xiao-Fang ^{[1
]}

Pan, Hu ^{[1
]}

Zhang, Heng ^{[1
]}

Yang, Song ^{[1
]}

机构：

[1] Guizhou Univ, State Key Lab Breeding Base Green Pesticide & Agr, Key Lab Green Pesticide & Agr Bioengn,Minist Educ, Ctr Res & Dev Fine Chem,State Local Joint Lab Com, Guiyang 550025, Peoples R China

来源：

RSC ADVANCES | 2017年 / 7卷 / 10期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; SOLID LEWIS-ACIDS; CATALYTIC TRANSFORMATION; HETEROGENEOUS CATALYSIS; SUGAR CONVERSION; METHYL LACTATE; LEVULINIC ACID; C-C; SITES; FE;

D O I：

10.1039/c6ra26469g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MIL-100(Fe) was used for the first time in the catalytic transformation of hexose sugars into lactic acid (LA). The as-synthesized MIL-100(Fe) was systematically characterized, and its superior morphological and textural properties were demonstrated to contribute greatly to the pronounced catalytic performance in fructose-to-LA conversion (up to 32% yield), as compared with other catalysts like Cu-BTC and MIL-100(Cr). The effects of reaction conditions including temperature, reaction time, and substrate loading were explored. In addition, MIL-100(Fe) could be easily reused for 4 cycles with no evident decrease in catalytic activity.

引用

页码：5621 / 5627

页数：7

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