MIL-100(Fe)-catalyzed efficient conversion of hexoses to lactic acid

被引：88
|
作者：
Huang, Shan [1 ]
Yang, Kai-Li [1 ]
Liu, Xiao-Fang [1 ]
Pan, Hu [1 ]
Zhang, Heng [1 ]
Yang, Song [1 ]
机构：
[1] Guizhou Univ, State Key Lab Breeding Base Green Pesticide & Agr, Key Lab Green Pesticide & Agr Bioengn,Minist Educ, Ctr Res & Dev Fine Chem,State Local Joint Lab Com, Guiyang 550025, Peoples R China
来源：
RSC ADVANCES | 2017年 / 7卷 / 10期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORKS; SOLID LEWIS-ACIDS; CATALYTIC TRANSFORMATION; HETEROGENEOUS CATALYSIS; SUGAR CONVERSION; METHYL LACTATE; LEVULINIC ACID; C-C; SITES; FE;
D O I：
10.1039/c6ra26469g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
MIL-100(Fe) was used for the first time in the catalytic transformation of hexose sugars into lactic acid (LA). The as-synthesized MIL-100(Fe) was systematically characterized, and its superior morphological and textural properties were demonstrated to contribute greatly to the pronounced catalytic performance in fructose-to-LA conversion (up to 32% yield), as compared with other catalysts like Cu-BTC and MIL-100(Cr). The effects of reaction conditions including temperature, reaction time, and substrate loading were explored. In addition, MIL-100(Fe) could be easily reused for 4 cycles with no evident decrease in catalytic activity.
引用
收藏
页码：5621 / 5627
页数：7
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