Photomediated controlled radical polymerization

被引：582

作者：

Pan, Xiangcheng ^{[1
]}

Tasdelen, Mehmet Atilla ^{[2
]}

Laun, Joachim ^{[3
]}

Junkers, Tanja ^{[3
,4
]}

Yagci, Yusuf ^{[5
,6
,7
]}

Matyjaszewski, Krzysztof ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, 4400 5th Ave, Pittsburgh, PA 15213 USA

[2] Yalova Univ, Dept Polymer Engn, Fac Engn, TR-77100 Yalova, Turkey

[3] Univ Hasselt, Inst Mat Res IMO, Polymer React Design Grp, Martelarenlaan 42, B-3500 Hasselt, Belgium

[4] IMEC, Div IMOMEC, Wetenschapspk 1, B-3590 Diepenbeek, Belgium

[5] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

[6] King Abdulaziz Univ, CEAMR, Fac Sci, Jeddah 21589, Saudi Arabia

[7] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia

来源：

PROGRESS IN POLYMER SCIENCE | 2016年 / 62卷

基金：

美国国家科学基金会;

关键词：

Photopolymerization; Radical polymerization; ATRP; RAFT; NMP; FRAGMENTATION CHAIN TRANSFER; TEMPERATURE RAFT POLYMERIZATION; PHOTOINDUCED ELECTRON-TRANSFER; PHOTOINIFERTER-MEDIATED POLYMERIZATION; LENGTH-DEPENDENT TERMINATION; VISIBLE-LIGHT PHOTOCATALYSIS; RING-OPENING POLYMERIZATION; METHYL-METHACRYLATE; BLOCK-COPOLYMERS; DISPERSION POLYMERIZATION;

D O I：

10.1016/j.progpolymsci.2016.06.005

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：73 / 125

页数：53

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