Photomediated controlled radical polymerization

被引：568
作者：
Pan, Xiangcheng [1 ]
Tasdelen, Mehmet Atilla [2 ]
Laun, Joachim [3 ]
Junkers, Tanja [3 ,4 ]
Yagci, Yusuf [5 ,6 ,7 ]
Matyjaszewski, Krzysztof [1 ]
机构：
[1] Carnegie Mellon Univ, Dept Chem, 4400 5th Ave, Pittsburgh, PA 15213 USA
[2] Yalova Univ, Dept Polymer Engn, Fac Engn, TR-77100 Yalova, Turkey
[3] Univ Hasselt, Inst Mat Res IMO, Polymer React Design Grp, Martelarenlaan 42, B-3500 Hasselt, Belgium
[4] IMEC, Div IMOMEC, Wetenschapspk 1, B-3590 Diepenbeek, Belgium
[5] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey
[6] King Abdulaziz Univ, CEAMR, Fac Sci, Jeddah 21589, Saudi Arabia
[7] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia
来源：
PROGRESS IN POLYMER SCIENCE | 2016年 / 62卷
基金：
美国国家科学基金会;
关键词：
Photopolymerization; Radical polymerization; ATRP; RAFT; NMP; FRAGMENTATION CHAIN TRANSFER; TEMPERATURE RAFT POLYMERIZATION; PHOTOINDUCED ELECTRON-TRANSFER; PHOTOINIFERTER-MEDIATED POLYMERIZATION; LENGTH-DEPENDENT TERMINATION; VISIBLE-LIGHT PHOTOCATALYSIS; RING-OPENING POLYMERIZATION; METHYL-METHACRYLATE; BLOCK-COPOLYMERS; DISPERSION POLYMERIZATION;
D O I：
10.1016/j.progpolymsci.2016.06.005
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：73 / 125
页数：53
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