Improvement of UV spectrophotometry methodology for the determination of total polycyclic aromatic compounds in contaminated soils

被引：13

作者：

Cloarec, O ^{[1
]}

Gonzalez, C ^{[1
]}

Touraud, E ^{[1
]}

Thomas, O ^{[1
]}

机构：

[1] Ecole Mines Ales, Lab Genie Environm Ind, F-30319 Ales, France

来源：

ANALYTICA CHIMICA ACTA | 2002年 / 453卷 / 02期

关键词：

polycyclic; aromatic hydrocarbons; soils; liquid chromatography; UV spectrometry;

D O I：

10.1016/S0003-2670(01)01432-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Solid phase extraction (SPE) and UV spectrophotometry is used for the determination of polycyclic aromatic hydrocarbons in soils. A combination of aminopropyl and octadecyl bonded silica in a double SPE cartridge system has been optimized and validated using a certified reference material. The quantification is carried out after a principal component regression. The calibration has been done on a set of 40 samples of contaminated soils and has been optimized by using cross-validation. The 3sigma- detection limit was found to be 4.5 mg kg(-1). (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：245 / 252

页数：8

共 19 条

[1]

Beebe K.R., 1998, CHEMOMETRICS PRACTIC

[2] Introduction to multivariate calibration in analytical chemistry [J].

Brereton, RG .

ANALYST, 2000, 125 (11) :2125-2154

[3] Evaluation of extraction and detection method for determining polynuclear aromatic hydrocarbons from coal tar contaminated soils [J].

Chen, CS ;

Rao, PSC ;

Lee, LS .

CHEMOSPHERE, 1996, 32 (06) :1123-1132

[4] USE OF DISPOSABLE CLEANUP COLUMNS FOR SELECTIVE REMOVAL OF HUMIC SUBSTANCES PRIOR TO MEASUREMENTS WITH A NITRATE ION-SELECTIVE ELECTRODE [J].

CSIKY, I ;

MARKOVARGA, G ;

JONSSON, JA .

ANALYTICA CHIMICA ACTA, 1985, 178 (02) :307-312

[5]

da Silva JCGE, 1998, ANAL LETT, V31, P2549

[6] Extraction of polycyclic aromatic hydrocarbons from soils: A comparison between focused microwave assisted extraction, supercritical fluid extraction, subcritical solvent extraction, sonication and Soxhlet techniques [J].

Dupeyron, S ;

Dudermel, PM ;

Couturier, D ;

Guarini, P ;

Delattre, JM .

INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 1999, 73 (03) :191-210

[7] Application of GC-MS and GC-AED to the evaluation of by-products formed by solar photo-fenton degradation of methyl tert-butyl ether in water [J].

Agüera, A ;

Mezcua, M ;

Hernando, D ;

Malato, S ;

Cáceres, J ;

Fernández-Alba, A .

INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2004, 84 (1-3) :149-159

[8]

Hildebrand J.H., 1964, SOLUBILITY NONELECTR

[9] Determination of polycyclic aromatic hydrocarbons in contaminated water and soil samples by immunological and chromatographic methods [J].

Knopp, D ;

Seifert, M ;

Väänänen, V ;

Niessner, R .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (10) :2035-2041

[10] Polycyclic aromatic hydrocarbons in waste waters and sewage sludge: Extraction and clean-up for HPLC analysis with fluorescence detection [J].

Manoli, E ;

Samara, C .

CHROMATOGRAPHIA, 1996, 43 (3-4) :135-142

← 1 2 →