A novel La3+-Zn2+-Al3+-MoO42- layered double hydroxides photocatalyst for the decomposition of dibenzothiophene in diesel oil

被引：3

作者：

Gao, Li-Guo ^{[1
]}

Gao, Ying-Ying ^{[2
]}

Song, Xiao-Li ^{[1
]}

Ma, Xiang-rong ^{[1
]}

机构：

[1] Yulin Univ, Dept Chem, Coll Chem & Chem Engn, Yulin, Peoples R China

[2] Shaanxi Univ Sci & Technol, Dept Chem, Coll Chem & Chem Engn, Xian, Shaanxi, Peoples R China

来源：

PETROLEUM SCIENCE AND TECHNOLOGY | 2018年 / 36卷 / 12期

关键词：

La3+-Zn2+-Al3+-MoO42- LDHs; photocatalytic; desulfurization; dibenzothiophene; ultraviolet light; DESULFURIZATION; OXIDATION;

D O I：

10.1080/10916466.2018.1447957

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A new type of photocatalyst, La3+-Zn2+-Al3+-MoO42- layered double hydroxide (LDH) (La:Zn:Al = 1:7:2), was prepared by a complexing agent-assisted homogeneous precipitation technique. The LDHs were used as catalysts for the desulfurization of diesel oil under UV irradiation. As revealed by the results, the catalyst showed superior desulfurization efficiency and recycling performance. Under UV irradiation, the desulfurization efficiency was 84% in 60min. In La3+-Zn2+-Al3+-MoO42- LDHs, the introduction of MoO42- increased the interlayer space for promoting the adsorption of dibenzothiophene, and MoO42- might act as the active sites for the oxidation of dibenzothiophene, resulting in the high desulfurization efficiency.

引用

页码：850 / 855

页数：6

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