Click chemistry on curdlan:: A regioselective and quantitative approach to develop artificial β-1,3-glucans with various functional appendages

被引:39
|
作者
Hasegawa, T
Umeda, M
Numata, M
Fujisawa, T
Haraguchi, S
Sakurai, K
Shinkai, S
机构
[1] Kyushu Univ, Grad Sch Engn, Dept Chem, Fukuoka 8128581, Japan
[2] Univ Kitakyushu, Fac Environm Engn, Dept Chem Proc & Environm, Wakamatsu Ku, Kitakyushu, Fukuoka 8080135, Japan
关键词
D O I
10.1246/cl.2006.82
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
beta-1,3-Glucans having various functional appendages (lactoside, ferrocene, pyrene. etc.) can be prepared in an convenient, quantitative, and regioselective manner through chemo-selective [3 + 2]-cycloadditions between 6-azido-6-deoxy-curdlan and various functional modules with a terminal alkyne.
引用
收藏
页码:82 / 83
页数:2
相关论文
共 2 条
  • [1] 'Click chemistry' on polysaccharides:: a convenient, general, and monitorable approach to develop (1→3)-β-D-glucans with various functional appendages
    Hasegawa, T
    Umeda, M
    Numata, M
    Li, C
    Bae, AH
    Fujisawa, T
    Haraguchi, S
    Sakurai, K
    Shinkai, S
    CARBOHYDRATE RESEARCH, 2006, 341 (01) : 35 - 40
  • [2] Click chemistry approach for the regioselective synthesis of iso-indoline-1,3-dione-linked 1,4 and 1,5 coumarinyl 1,2,3-triazoles and their photophysical properties
    Anand, Ashish
    Kulkarni, Manohar V.
    SYNTHETIC COMMUNICATIONS, 2017, 47 (07) : 722 - 733