Poly[cadmium(II)-μ-4,4′-oxydianiline-N:N′-di-μ-thiocyanato-N:S]

被引：1
作者：
Chen, HJ [1 ]
Yu, WJ
Chen, XM
Zheng, WJ
机构：
[1] Jinan Univ, Dept Chem, Guangzhou 510632, Peoples R China
[2] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2001年 / 57卷 / 11期
关键词：
D O I：
10.1107/S0108270101014305
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title polymeric complex, [Cd(SCN)(2)(C12H12N2O)], exhibits a three-dimensional framework in which each Cd-II atom is bridged by two eta -1,3-(SCN)(-) groups, forming a double-stranded chain. The unique Cd-II atom lies on an inversion centre and the coordination sphere is completed by two terminal N atoms from two different 4,4'-oxydianiline (4,4'-Oda) ligands, furnishing a CdS2N4 octahedral geometry. Adjacent polymeric double-stranded chains are linked via the 4,4'-Oda ligands, which lie across twofold rotation axes.
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页码：1285 / 1287
页数：3
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