Investigation of deuterium isotope effects in the carbon dioxide reforming of methane to syngas over rhodium catalysts

被引：0
作者：
Wang, HY
Au, CT
机构：
[1] XIAMEN UNIV,DEPT CHEM,XIAMEN 361005,PEOPLES R CHINA
[2] HONG KONG BAPTIST UNIV,DEPT CHEM,KOWLOON,HONG KONG
来源：
CHINESE CHEMICAL LETTERS | 1996年 / 7卷 / 11期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Deuterium isotope effects in the CO2-reforming of methane to syngas were first investigated over SiO2-supported rhodium catalysts. Normal deuterium isotope effect was more noticeable on the methane conversion reaction than on the CO formation reaction, while there was no such effect on the CO2 conversion reaction. It can be concluded that the dissociation of the C-H bond in methane is a key step and some CO is formed by the reverse water-gas shift reaction.
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页码：1047 / 1050
页数：4
相关论文
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