[Cr(Salen)] as a 'bridge' between asymmetric catalysis, Lewis acids and redox processes

被引：120
作者：
Bandini, M [1 ]
Cozzi, PG [1 ]
Umani-Ronchi, A [1 ]
机构：
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 09期
关键词：
D O I：
10.1039/b109945k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An overview focused on the synthesis, structural features and catalytic applications of chiral [Cr(Salen)] complexes is presented. Key aspects of modern organic chemistry such as Lewis acids, asymmetric catalysis and redox processes are strictly connected with chronium-Schiff base complexes. Among the asymmetric transformations mediated by [Cr(Salen)] complexes, Diels-Alder and hetero-Diels-Alder reactions, ARO of epoxides, kinetic resolution of meso-epoxides and Nozki-Hyama reactions are taken into account.
引用
收藏
页码：919 / 927
页数：9
相关论文
共 107 条
[1]   A highly chemoselective oxidation of alcohols to carbonyl products with iodosobenzene diacetate mediated by chromium(III)(salen) complexes:: Synthetic and mechanistic aspects [J].
Adam, W ;
Hajra, S ;
Herderich, M ;
Saha-Möller, CR .
ORGANIC LETTERS, 2000, 2 (18) :2773-2776
[2]   Asymmetric hetero Diels-Alder reaction using chiral cationic metallosalen complexes as catalysts [J].
Aikawa, K ;
Irie, R ;
Katsuki, T .
TETRAHEDRON, 2001, 57 (05) :845-851
[3]  
[Anonymous], COLLECT CZECH CHEM C
[4]   Group 13 compounds incorporating salen ligands [J].
Atwood, DA ;
Harvey, MJ .
CHEMICAL REVIEWS, 2001, 101 (01) :37-52
[5]   Chromium vinylidene carbenoids: Generation, characterization, and reactivity. First evidence for an internal proton return phenomenon with vinylidene carbenoids [J].
Baati, R ;
Barma, DK ;
Falck, JR ;
Mioskowski, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (37) :9196-9197
[6]  
Bandini M, 1999, ANGEW CHEM INT EDIT, V38, P3357, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3357::AID-ANIE3357>3.0.CO
[7]  
2-W
[8]   Highly diastereoselective pinacol coupling of aldehydes catalyzed by titanium Schiff base complexes [J].
Bandini, M ;
Cozzi, PG ;
Morganti, S ;
Umani-Ronchi, A .
TETRAHEDRON LETTERS, 1999, 40 (10) :1997-2000
[9]   Cr(Salen)-catalyzed addition of 1,3-dichloropropene to aromatic aldehydes, a simple access to optically active vinyl epoxides [J].
Bandini, M ;
Cozzi, PG ;
Melchiorre, P ;
Morganti, S ;
Umani-Ronchi, A .
ORGANIC LETTERS, 2001, 3 (08) :1153-1155
[10]   Enantioselective catalytic addition of allyl organometallic reagents to aldehydes promoted by [Cr(Salen)]: the hidden role played by weak Lewis acids in metallo-Salen promoted reactions [J].
Bandini, M ;
Cozzi, PG ;
Umani-Ronchi, A .
TETRAHEDRON, 2001, 57 (05) :835-843
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